Chinese Journal of Magnetic Resonance ›› 2005, Vol. 22 ›› Issue (1): 61-66.

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Detection of Distorted Tetrahedral-Coordinate Aluminum in Dealuminated Mordenite by 27Al 3Q MAS NMR

  

  1. 1.Department of Chemistry, 2.Department of Physics, Nankai University, Tianjin, 300071, China
  • Received:2004-09-13 Revised:2004-10-25 Online:2005-03-05 Published:2005-03-05
  • Supported by:

    国家自然科学基金(29803004,20233030,20373029), 教育部高等学校骨干教师基金(GG-703-10055-1008)资助项目.

Abstract:

27Al MAS and 3Q MAS NMR spectroscopy was applied to study the aluminum coordination in dealuminated zeolite mordenite and amorphous silica alumina. A signal ascribed to distorted tetrahedral coordinate Al (DTA) was detected. By comparison with amorphous silica alumina, it was found that the presence of distorted tetrahedral coordinate species is a typical feature in crystalline zeolites after activation and dealumination. From these experimental results we suggest that the DTA species, which are absent in amorphous silicaalumina, locate at the interface between the crystalline framework lattice and the extra-framework species formed by dealumination.

Key words: NMR, multiple quantum magic angle spinning (3Q MAS) NMR, mordenite, dealumination, distorted tetrahedral-coordinated Al (DTA)

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