Chinese Journal of Magnetic Resonance

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Simulation of Restricted Diffusion of Water Molecules in Micropores

ZHANG Zong-fu,XIAO Li-zhi∗,LIU Hua-bing,LI Xin,DENG Feng,XU Wei,AN Tian-lin,CHENG Jia-jie   

  1. State Key Laboratory of Petroleum Resource and Prospecting, China University of Petroleum, Beijing 102249, China
  • Received:2012-12-12 Revised:2012-12-29 Online:2014-03-05 Published:2014-03-05
  • About author:XIAO Li-zhi, Tel: 010 89733305, E-mail: xiaolizhi@cup.edu.cn.
  • Supported by:

    国家自然科学基金资助项目(41074102),高等学校学科创新引智计划“111 计划”资助项目(B13010),长江学者和创新团队发展计划资助项目.

Abstract:

In petroleum exploration, diffusion coefficient measured with NMR techniques is often used to identify fluid types (e.g., oil, water, and gas) and to calculate the saturation degree of reservoir rocks. In the micro-pores, however, the apparent or effective diffusion coefficient must be lower than the free diffusion coefficient. In this paper, the relationship between pore size and apparent diffusion coefficient is simulated using the finite difference and random walk methods. The effects of restricted diffusion on the accuracy of the petrophysical parameter calculations were analyzed under the well-logging and laboratory
conditions. Lastly, the application conditions and advantages of the two simulation methods were discussed.

Key words: NMR, restricted diffusion, micropore, finite difference, random walk

CLC Number: