Structure Determination of Three Anhydrosucrose Derivatives by NMR

Abstract

Abstract:

The structures of 1, 4∶3, 6-dianhydro-β-D- fructofuranosyl 4-chloro-4-deoxy-α-D-galactopyranoside( 1), 1, 4∶3, 6-dianhydro-β-D-fructofuranosyl 3, 6-anhydro-4-chloro-4-deoxy-α-D-galactopyranoside (2) and 1, 6-dichloro-1, 6-dideoxy-β-D-fructofuranosyl 3, 6-anhydro-4-chloro-4-deoxy-α-D-galactopyranoside (3) were elucidated using 1D and 2D NMR spectroscopy (¹H NMR, ¹³C NMR, DEPT-135, ¹H-¹H COSY, HSQC, HMBC) and HRMS spectra. ¹H and ¹³C chemical shifts of these compounds were assigned.

Key words: NMR, assignments, anhydrosucrose, sucralose, 4, 6, 1′, 6′-tetrachloro- 4, 6, 1′, 6′-tetradeoxy-galactosucrose

CLC Number:

O641

Cite this article

LIU Feng-Wu, ZHANG Jing-Yu, LIU Hong-Min, SONG Xiao-Ping. Structure Determination of Three Anhydrosucrose Derivatives by NMR[J]. Chinese Journal of Magnetic Resonance, 2005, 22(2): 149-154.

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References

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