固体核磁共振技术在锡硅分子筛表征中的应用

doi:10.11938/cjmr20212926

波谱学杂志 ›› 2021, Vol. 38 ›› Issue (4): 571-584.doi: 10.11938/cjmr20212926

• • 上一篇

固体核磁共振技术在锡硅分子筛表征中的应用

肖瑶^1,²,夏长久³,易先锋^1,*(),刘凤庆^1,²,刘尚斌⁴,郑安民^1,*()

1. 中国科学院精密测量科学与技术创新研究院, 武汉物理与数学研究所, 波谱与原子分子物理国家重点实验室, 湖北武汉 430071
2. 中国科学院大学, 北京 100049
3. 中国石油化工股份有限公司石油化工科学研究院, 石油化工催化材料与反应工程国家重点实验室, 北京 100083
4. 原子与分子科学研究所, 台湾台北 10617

收稿日期:2021-06-28 出版日期:2021-12-05 发布日期:2021-08-14
通讯作者: 易先锋,郑安民 E-mail:yxf@wipm.ac.cn;zhenganm@wipm.ac.cn
基金资助:
石油化工催化材料与反应工程国家重点实验室（中国石油化工股份有限公司石油化工科学研究院）开放基金课题资助(33600000-20-ZC0607-0024);国家自然科学基金资助项目(22032005);国家自然科学基金资助项目(21802164)

Progress in the Studies on Sn-Zeolites by Solid-State Nuclear Magnetic Resonance

Yao XIAO^1,²,Chang-jiu XIA³,Xian-feng YI^1,*(),Feng-qing LIU^1,²,Shang-bin LIU⁴,An-min ZHENG^1,*()

1. State Key Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Innovation Academy for Precision Measurement Science and Technology, Chinese Academy of Sciences, Wuhan 430071, China
2. University of Chinese Academy of Sciences, Beijing 100049, China
3. State Key Laboratory of Catalytic Materials and Reaction Engineering, Research Institute of Petroleum Processing, SINOPEC, Beijing 100083, China
4. Institute of Atomic and Molecular Sciences, Taipei 10617, China

Received:2021-06-28 Online:2021-12-05 Published:2021-08-14
Contact: Xian-feng YI,An-min ZHENG E-mail:yxf@wipm.ac.cn;zhenganm@wipm.ac.cn

摘要/Abstract

摘要：

生物质等绿色资源的高效转化利用是催化科学的重要发展方向.锡硅分子筛因具有优良的催化性能而得到相关研究者的普遍关注.准确构建催化剂活性中心结构/酸性与催化反应性能之间的构效关系是新型高效催化剂设计与研发的基础.固体核磁共振（NMR）是研究分子筛活性中心局域结构、酸特性与催化反应机理的重要手段.本文简述了近年来固体NMR技术在锡硅分子筛研究领域的一系列主要进展，并进行了展望.

关键词: 固体核磁共振, 锡硅分子筛, 活性中心结构, 酸特性, 反应机理

Abstract:

Due to their excellent catalytic performances in the conversion of biomass molecules such as glucose and lactic acid, the Sn-containing zeolite catalysts have received wide attention. Understanding detailed structures and acidity properties of the active sites and the corresponding catalytic reaction mechanisms is a critical step in developing fundamental insights into the catalytic function and exploiting more highly active zeolite catalysts. Solid-state nuclear magnetic resonance (NMR) spectroscopy provides useful information on the local structures and acidity properties of active centers, as well as the catalytic reaction mechanisms in zeolites. This review briefly introduces the application of solid-state NMR technique in the studies on Sn-containing zeolites. Further challenges and perspectives are also discussed.

Key words: solid-state nuclear magnetic resonance (NMR), Sn-zeolite, active center, acidity, reaction mechanism

中图分类号:

O482.53

肖瑶,夏长久,易先锋,刘凤庆,刘尚斌,郑安民. 固体核磁共振技术在锡硅分子筛表征中的应用[J]. 波谱学杂志, 2021, 38(4): 571-584.

Yao XIAO,Chang-jiu XIA,Xian-feng YI,Feng-qing LIU,Shang-bin LIU,An-min ZHENG. Progress in the Studies on Sn-Zeolites by Solid-State Nuclear Magnetic Resonance[J]. Chinese Journal of Magnetic Resonance, 2021, 38(4): 571-584.

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固体核磁共振技术在锡硅分子筛表征中的应用

Progress in the Studies on Sn-Zeolites by Solid-State Nuclear Magnetic Resonance

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