Chinese Journal of Magnetic Resonance ›› 2023, Vol. 40 ›› Issue (1): 30-38.doi: 10.11938/cjmr20223005
• Articles • Previous Articles Next Articles
CI Jie,YANG Xue,XIN Jiaxiang,WEI Daxiu*(),YAO Yefeng#()
Received:
2022-06-07
Published:
2023-03-05
Online:
2022-07-14
Contact:
WEI Daxiu,YAO Yefeng
E-mail:dxwei@phy.ecnu.edu.cn;yfyao@phy.ecnu.edu.cn.
CLC Number:
CI Jie,YANG Xue,XIN Jiaxiang,WEI Daxiu,YAO Yefeng. Preparation and Lifetime Studies of the Singlet State of Five Spins in Hexene Molecules Used to Guide the Preservation of the Parahydrogen-induced Nuclear Polarization State[J]. Chinese Journal of Magnetic Resonance, 2023, 40(1): 30-38.
Fig. 2
The amplitudes and phases of different optimal control pulses, and the pulse sequence for the experiments. (a1), (c1), (e1) are the amplitudes of unitary transformation ${{U}_{\text{bc}}}$,${{U}_{\text{ac}}}$,${{U}_{\text{ab}}}$, respectively. (a2), (c2), (e2) are the phases of unitary transformation${{U}_{\text{bc}}}$,${{U}_{\text{ac}}}$,${{U}_{\text{ab}}}$, respectively. (b1), (d1), (f1) are the amplitudes of unitary transformation${{{U}'}_{\text{bc}}}$,${{{U}'}_{\text{ac}}}$,${{{U}'}_{\text{ab}}}$, respectively. (b2), (d2), (f2) are the phases of unitary transformation${{{U}'}_{\text{bc}}}$,${{{U}'}_{\text{ac}}}$,${{{U}'}_{\text{ab}}}$, respectively. (g) The experimental pulse sequence
Table 2
The lifetime values of singlet states and the longitudinal relaxation time values
时间/s | 2.52±0.03 | 5.93±0.08 | 11.02±0.18 | 8.61±0.07 | 11.54±0.42 | 11.52±0.31 | 14.22±0.41 |
[1] |
YAO H Y Y, WANG J Q, YIN J Y, et al. A review of NMR analysis in polysaccharide structure and conformation: Progress, challenge and perspective[J]. Food Res Int, 2021, 143: 110290.
doi: 10.1016/j.foodres.2021.110290 |
[2] | LIU Q Y, LIU S Y, LUO Y K, et al. Pulsed-field nuclear magnetic resonance: Status and prospects[J]. Matter Radiat Extrem, 2021, 6(2): 67-86. |
[3] | HERRLING M P, LACKNER S, NIRSCHL H, et al. Recent NMR/MRI studies of biofilm structures and dynamics[M]. WEBB G A Ed. Annual Reports on NMR Spectroscopy. Academic Press, 2019: 163-213. |
[4] |
DOWNES D P, COLLINS J H P, LAMA B, et al. Characterization of brain metabolism by nuclear magnetic resonance[J]. Chemphyschem, 2019, 20(2): 216-230.
doi: 10.1002/cphc.201800917 pmid: 30536696 |
[5] |
BHASKAR N D, HAPPER W, MCCLELLAND T. Efficiency of spin exchange between rubidium spins and 129Xe nuclei in a gas[J]. Phys Rev Lett, 1982, 49(1): 25-28.
doi: 10.1103/PhysRevLett.49.25 |
[6] |
GRIESINGER C, BENNATI M, VIETH H M, et al. Dynamic nuclear polarization at high magnetic fields in liquids[J]. Prog Nucl Magn Reson Spectrosc, 2012, 64: 4-28.
doi: 10.1016/j.pnmrs.2011.10.002 |
[7] |
GRIFFIN R G. Dynamic nuclear polarization at 9T using a novel 250 gyrotron microwave source[J]. J Magn Reson, 2011, 213(2): 410-412.
doi: 10.1016/j.jmr.2011.08.015 pmid: 22152359 |
[8] |
MOMPEAN M, SANCHEZ-DONOSO R M, DE LA HOZ A, et al. Pushing nuclear magnetic resonance sensitivity limits with microfluidics and photo-chemically induced dynamic nuclear polarization[J]. Nat Commun, 2018, 9(1): 108.
doi: 10.1038/s41467-017-02575-0 |
[9] |
DUCKETT S B, WOOD N J. Parahydrogen-based NMR methods as a mechanistic probe in inorganic chemistry[J]. Coordin Chem Rev, 2008, 252(21-22): 2278-2291.
doi: 10.1016/j.ccr.2008.01.028 |
[10] |
PRAVDIVTSEV A N, BUNTKOWSKY G, DUCKETT S B, et al. Parahydrogen-induced polarization of amino acids[J]. Angew Chem Int Ed Engl, 2021, 60(44): 23496-23507.
doi: 10.1002/anie.202100109 |
[11] | CANET D, AROULANDA C, MUTZENHARDT P, et al. Para-hydrogen enrichment and hyperpolarization[J]. Concept Magn Reson A, 2006, 28a(5): 321-330. |
[12] |
KOVTUNOV K V, POKOCHUEVA E V, SALNIKOV O G, et al. Hyperpolarized NMR spectroscopy: d-DNP, PHIP, and SABRE techniques[J]. Chem Asian J, 2018, 13(15): 1857-1871.
doi: 10.1002/asia.201800551 |
[13] |
DECHENT J F, BULJUBASICH L, SCHREIBER L M, et al. Proton magnetic resonance imaging with para-hydrogen induced polarization[J]. Phys Chem Chem Phys, 2012, 14(7): 2346-2352.
doi: 10.1039/c2cp22822j pmid: 22240943 |
[14] |
GLOGGLER S, COLELL J, APPELT S. Para-hydrogen perspectives in hyperpolarized NMR[J]. J Magn Reson, 2013, 235: 130-142.
doi: 10.1016/j.jmr.2013.07.010 pmid: 23932399 |
[15] | TIAN J X, LIU W Q, SONG Y H, et al. Implementation of deutsch algorithm using para-hydrogen induced polarization[J]. Chinese J Magn Reson, 2015, 32(4): 618-627. |
田佳欣, 刘文卿, 宋艳红, 等. 利用仲氢诱导极化技术实现Deutsch算法[J]. 波谱学杂志, 2015, 32(4): 618-627. | |
[16] | HU H, WANG W Y, XU J, et al. 1, 3-Butadienen hydrogenation on supported Pd-Sn bimetallic catalysts investigated by parahydrogen-induced polarization[J]. Chinese J Magn Reson, 2022, 39(2): 133-143. |
胡涵, 王伟宇, 徐君, 等. Pd-Sn双金属催化剂催化1, 3-丁二烯加氢反应的仲氢诱导极化研究[J]. 波谱学杂志, 2022, 39(2): 133-143. | |
[17] |
ROTH M, KINDERVATER P, RAICH H P, et al. Continuous 1H and 13C signal enhancement in NMR spectroscopy and MRI using parahydrogen and hollow-fiber membranes[J]. Angew Chem Int Ed, 2010, 122: 8536-8540.
doi: 10.1002/ange.201002725 |
[18] |
ARIYASINGHA N M, SALNIKOV O G, KOVTUNOV K V, et al. Relaxation dynamics of nuclear long-lived spin states in propane and propane-d6 hyperpolarized by parahydrogen[J]. J Phys Chem C Nanomater Interfaces, 2019, 123(18): 11734-11744.
doi: 10.1021/acs.jpcc.9b01538 |
[19] |
PILEIO G, CARRAVETTA M, LEVITT M H. Storage of nuclear magnetization as long-lived singlet order in low magnetic field[J]. Proc Natl Acad Sci U S A, 2010, 107(40): 17135-17139.
doi: 10.1073/pnas.1010570107 |
[20] |
BENGS C, SABBA M, JERSCHOW A, et al. Generalised magnetisation-to-singlet-order transfer in nuclear magnetic resonance[J]. Phys Chem Chem Phys, 2020, 22(17): 9703-9712.
doi: 10.1039/d0cp00935k pmid: 32329499 |
[21] |
DEVIENCE S J, WALSWORTH R L, ROSEN M S. Preparation of nuclear spin singlet states using spin-lock induced crossing[J]. Phys Rev Lett, 2013, 111(17): 173002.
doi: 10.1103/PhysRevLett.111.173002 |
[22] |
PRAVDIVTSEV A N, KIRYUTIN A S, YURKOVSKAYA A V, et al. Robust conversion of singlet spin order in coupled spin-1/2 pairs by adiabatically ramped RF-fields[J]. J Magn Reson, 2016, 273: 56-64.
doi: S1090-7807(16)30194-X pmid: 27750072 |
[23] | HU K R, YANG X, HUANG Z M, et al. Preparing nuclear spin singlet state in a three-spin system and its application in 2D spectrum[J]. Chinese J Magn Reson, 2022, 39(1): 96-107. |
胡凯瑞, 杨雪, 黄志明, 等. 三自旋体系核自旋单重态的制备与单重态二维谱的实现[J]. 波谱学杂志, 2022, 39(1): 96-107. | |
[24] |
CARRAVETTA M, LEVITT M H. Theory of long-lived nuclear spin states in solution nuclear magnetic resonance. I. Singlet states in low magnetic field[J]. J Chem Phys, 2005, 122(21): 214505.
doi: 10.1063/1.1893983 |
[25] |
KHANEJA N, REISS T, KEHLET C, et al. Optimal control of coupled spin dynamics: design of NMR pulse sequences by gradient ascent algorithms[J]. J Magn Reson, 2005, 172(2): 296-305.
pmid: 15649756 |
[26] |
TOSNER Z, VOSEGAARD T, KEHLET C, et al. Optimal control in NMR spectroscopy: numerical implementation in SIMPSON[J]. J Magn Reson, 2009, 197(2): 120-134.
doi: 10.1016/j.jmr.2008.11.020 pmid: 19119034 |
[27] |
STEVANATO G, ROY S S, HILL-COUSINS J, et al. Long-lived nuclear spin states far from magnetic equivalence[J]. Phys Chem Chem Phys, 2015, 17(8): 5913-5922.
doi: 10.1039/c4cp05704j pmid: 25633837 |
[1] | WANG Feng,LIU Tingwei,XU Yajie,YU Peng,WANG Ya,PENG Bowen,YANG Xiaodong. A Miniaturised NMR RF Probe Design with External Field-locking Channel [J]. Chinese Journal of Magnetic Resonance, 2023, 40(3): 332-340. |
[2] | Yuanfang WANG, Xiaohua WANG, Chang SHU, Xu ZHANG, Maili LIU, Danyun ZENG. The Aggregation of ATAD2 Bromodomain in Solution [J]. Chinese Journal of Magnetic Resonance, 2023, 40(2): 169-178. |
[3] | Chang ZHAO, Zhou GONG. Investigation of Dynamic Structure of Protein Encountering Complex with Paramagnetic NMR [J]. Chinese Journal of Magnetic Resonance, 2023, 40(2): 148-157. |
[4] | ZHAN Jianhua,HU Qin,ZHU Qinjun,JIANG Bin,ZHANG Xu,LIU Maili. Track the Conformational Change of Unlabeled Yeast Cytochrome c in Cell Homogenate Using NMR [J]. Chinese Journal of Magnetic Resonance, 2023, 40(1): 22-29. |
[5] | Xiao-yang ZHANG, Shou-quan YAO, Jun-cheng XU, Yu JIANG. Magnetic Field Locking System Based on Fluxgate and Time Domain Digital Frequency Discrimination [J]. Chinese Journal of Magnetic Resonance, 2022, 39(4): 448-458. |
[6] | Yun-shan PEI, Cai ZHANG, Xiao-li LIU, Kai CHENG, Ze-ting ZHANG, Cong-gang LI. Inhibition of α-Synuclein Aggregation by the Interaction Between Protein Disulfide Isomerase and α-Synuclein [J]. Chinese Journal of Magnetic Resonance, 2022, 39(4): 381-392. |
[7] | Han HU,Wei-yu WANG,Jun XU,Feng DENG. 1, 3-Butadienen Hydrogenation on Supported Pd-Sn Bimetallic Catalysts Investigated by Parahydrogen-induced Polarization [J]. Chinese Journal of Magnetic Resonance, 2022, 39(2): 133-143. |
[8] | Qian XU,Lang CHEN,Xiang-ying HU,Cong-gang LI,Yi-xiang LIU,Ling JIANG. The Effect of T69E-mimicked Phosphorylation on the Interaction Between Bcl-2 and Nur77 [J]. Chinese Journal of Magnetic Resonance, 2022, 39(1): 87-95. |
[9] | Kai-rui HU,Xue YANG,Zhi-ming HUANG,Jia-xiang XIN,Da-xiu WEI,Ye-feng YAO. Preparing Nuclear Spin Singlet State in a Three-spin System and Its Application in 2D Spectrum [J]. Chinese Journal of Magnetic Resonance, 2022, 39(1): 96-107. |
[10] | Xiao-qing LIN,Shi-jia DU,Hao-lin ZHAN,Yu-qing HUANG,Zhong CHEN. Two-Dimensional Homonuclear Orthogonal-Pattern Phase-Sensitive J-Resolved NMR Spectroscopy Based on Pure Shifts [J]. Chinese Journal of Magnetic Resonance, 2021, 38(4): 448-459. |
[11] | Yao XIAO,Chang-jiu XIA,Xian-feng YI,Feng-qing LIU,Shang-bin LIU,An-min ZHENG. Progress in the Studies on Sn-Zeolites by Solid-State Nuclear Magnetic Resonance [J]. Chinese Journal of Magnetic Resonance, 2021, 38(4): 571-584. |
[12] | Xiao-dong HU,Wen-xian LAN,Chun-xi WANG,Chun-yang CAO. Research Advance and NMR Studies of Anti-Cancer Small Molecules Targeting c-MYC G4-DNA [J]. Chinese Journal of Magnetic Resonance, 2021, 38(4): 503-513. |
[13] | Jia-min WU,Yu-cheng HE,Zheng XU,Yan-he ZHU,Wen-zheng JIANG. A Wide-Band Matching Method for Radio Frequency Coils Used in Soil Moisture Measurement [J]. Chinese Journal of Magnetic Resonance, 2021, 38(3): 414-423. |
[14] | Zi-hao WANG,He XU,Tao WANG,Shan-zhong YANG,Yun-sheng DING,Hai-bing WEI. NMR Spectroscopic Studies on (exo, endo) C-2 Monosubstituted Norbornene Derivatives [J]. Chinese Journal of Magnetic Resonance, 2021, 38(3): 323-335. |
[15] | Chong-wu WANG,Xi HUANG,Lei SHI,Shi-zhen CHEN,Xin ZHOU. Cathepsin B Triggered Hyperpolarization 129Xe MRI Probe for Ultra-Sensitive Lung Cancer Cells Detection [J]. Chinese Journal of Magnetic Resonance, 2021, 38(3): 336-344. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||