Chinese Journal of Magnetic Resonance ›› 2020, Vol. 37 ›› Issue (1): 16-27.doi: 10.11938/cjmr20192782

• Review Articles • Previous Articles     Next Articles

Progress in Solid-State NMR Studies of Monoclinic Lithium Vanadium Phosphate

LIN Ze-yu, HUO Hua, WANG Qi-hang   

  1. MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China
  • Received:2019-09-17 Online:2020-03-05 Published:2019-11-07
  • Supported by:
    the National Natural Science Foundation of China (21673065, 21403045, 21573013, 91745202)

Abstract: Monoclinic lithium vanadium phosphate is a promising cathode material for lithium-ion batteries, which has been widely studied in the past two decades. Solid-state nuclear magnetic resonance (SSNMR) is an excellent method to investigate the local environments of target nuclei and the short/long range structural changes of materials. In this short review, SSNMR studies on a few important aspects of monoclinic lithium vanadium phosphate, including charge-discharge mechanism, lithium mobility/dynamics, carbon coating, cation doping and theoretical calculation on NMR shifts, are briefly covered.

Key words: solid-state nuclear magnetic resonance, lithium ion battery, cathode material, review, lithium vanadium phosphate

CLC Number: