波谱学杂志 ›› 2015, Vol. 32 ›› Issue (2): 228-247.doi: 10.11938/cjmr20150207

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固体核磁共振谱学研究层状双氢氧化物

郁桂云1,彭路明2*   

  1. 1. 盐城工学院 化工学院,盐城 224051;
    2. 南京大学 化学化工学院,介观化学教育部重点实验室,南京210093
  • 收稿日期:2015-02-11 修回日期:2015-05-11 出版日期:2015-06-05 发布日期:2015-06-05
  • 作者简介:*通讯联系人:彭路明,电话:+86-25-83686793, E-mail: luming@nju.edu.cn.
  • 基金资助:

    The National Basic Research Program of China (2013CB934800), the National Natural Science Foundation of China (NSFC) (21073083, 20903056 and 21222302).

Solid-State NMR Studies of Layered Double Hydroxides: A Review

YU Gui-yun1,PENG Lu-ming2*   

  1. 1. School of Chemical Engineering, Yancheng Institute of Technology, Yancheng 224051;
    2. Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093
  • Received:2015-02-11 Revised:2015-05-11 Online:2015-06-05 Published:2015-06-05
  • About author:YU Gui-yun(1979-), female, born in Jiangsu, PhD., her research focuses on solid-state NMR and layered materials,E-mail: yuguiyun1@163.com. *Corresponding author:PENG Lu-ming, Tel: +86-25-83686793, E-mail: luming@nju.edu.cn.
  • Supported by:

    The National Basic Research Program of China (2013CB934800), the National Natural Science Foundation of China (NSFC) (21073083, 20903056 and 21222302).

摘要:

层状双氢氧化物(LDHs)作为一类非常重要的无机超分子材料,已经被广泛应用于催化、离子交换、生命科学等众多领域.固体核磁共振谱学是研究层状双氢氧化
物局域结构和动态特征的一种强有力手段,提供了非常丰富的信息.特别是最近,借助固体核磁共振在探索层状双氢氧化物的结构方面取得了非常重要的进展(如:阳离子的有序性信息).该文主要介绍了最近40 年来固体核磁共振研究层状双氢氧化物方面的重要进展.

关键词: 固体核磁共振, 层状双氢氧化物, 局部结构, 动态特征

Abstract:

Layered double hydroxides (LDHs) are very important inorganic supramolecular materials that have widespread applications including catalysis, ion exchange and biological sciences. Solid-state NMR spectroscopy has been a powerful tool for the investigations of local structure and dynamics of LDHs, and has provided rich information. In particular, key advances (e.g., cation ordering information) have been made with solid-state NMR only very recently. This review introduces significant progress in the solid-state NMR studies of LDHs in the last 40 years.

Key words: solid-state NMR, Layered double hydroxides (LDHs), local structure, dynamics

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