时间分辨CIDNP技术

波谱学杂志

时间分辨CIDNP技术

郭小永^1,2, 严宝珍², 郭洪玲², 田秋¹, 刘扬^1*

1.中国科学院化学研究所，分子科学中心分子动态与稳态结构国家重点实验室，北京 100080; 2.北京化工大学理学院，北京 100029

收稿日期:2002-06-26 修回日期:2002-08-29 出版日期:2003-03-05 发布日期:2003-03-05
作者简介:郭小永（1975-），男，陕西人，硕士研究生，分析化学专业
基金资助:
国家重点基础规划项目(G1998010100)与国家自然科学基金资助项目(39890390)

THE TECHNIQUE OF TIME RESOLVED CHEMICALLY INDUCED DYNAMIC POLARIZATION (CIDNP)

GUO Xiao-yong^1,2, YAN Bao-zhen², GUO Hong-ling², TIAN Qiu¹, LIU Yang^1*

1.Institute of Chemistry, The Chinese Acad. of Science, Beijing 100080, China;
2.Faculty of Sciences, Beijing University of Chemical Technology, Beijing 100029, China

Received:2002-06-26 Revised:2002-08-29 Online:2003-03-05 Published:2003-03-05
Supported by:
国家重点基础规划项目(G1998010100)与国家自然科学基金资助项目(39890390)

摘要/Abstract

摘要：

简要综述了时间分辨CIDNP（Time Resolved Chemically Induced Dynamic Polarization Effect）技术的发展概况、原理、实验及其应用.

关键词: 核磁共振, 化学诱导动态核极化, 时间分辨, 变换外磁场

Abstract:

The general situation, principles, experimental aspects and applications of time-resolved chemically induced dynamic polarization (CIDNP) is briefly reviewed.

Key words: NMR, CIDNP, time-resolved chemically induced dynamic polarization, SEMF

中图分类号:

O482.53

郭小永, 严宝珍, 郭洪玲, 田秋, 刘扬. 时间分辨CIDNP技术[J]. 波谱学杂志.

GUO Xiao-yong, YAN Bao-zhen, GUO Hong-ling, TIAN Qiu1, LIU Yang. THE TECHNIQUE OF TIME RESOLVED CHEMICALLY INDUCED DYNAMIC POLARIZATION (CIDNP)[J]. Chinese Journal of Magnetic Resonance.

［1］唐有祺，徐广智. 活泼中间体结构的研究方法［M］. 昆明：云南科技出版社，1990. p108-122.

［2］Bargon J, Fischerand H, Johnsen U Z. Natarforsch［J］, 1967,22a:1551.

［3］Ward H R. Radical Cyclization of an Acetylene［J］. J Am Chem Soc, 1967,89:5517-5518.

［4］Kaptein R, Oosterhoff J L. Chemically Induced Dynamic Nuclear Polarzation in Five Alkyl Radicals［J］. Chem Phys Letters, 1969, 4:195-214.

［5］Frank J Adrian. Role of Diffusion-controlled Reaction in Chemically Induced Nuclear Spin Polarization［J］. J Chem Phys, 1970, 53:3374-3375.

［6］Kaptein R. Chemically Induced Dynamic Nuclear Polarzation. VIII. Spin Dynamics and Diffusion of Radical Pairs. J Am Chem Soc［J］, 1972,94(18):6251-6262.

［7］Schaeublin S, Wokaun A, Ernst R R. The creation of off-diagonal elements in chemically induced dynamic nuclear polarization experiments［J］. Chem Phys, 1976,14:285-293.

［8］Closs G L, Miller R J. Laser Flash Photolysis with NMR Detection. Microsecond Time-Resolved CIDNP: Separation of Geminate and Random-Phase Processes［J］. J Am Chem Soc,1979,101:1639-1641.

［9］Closs Gerhard L, Milier Robert J, Redwine O David. Time-Resolved CIDNP: Application to Radical and Biradical Chemistry［J］. Acc Chem Res, 1985,18:196-202.

［10］Kaptein R. Simple Rules for Chemically Induced Dynamic Nuclear Polarization［J］. J Chem Soc Chem Commun, 1971. 732-733.

［11］刘中立. 化学诱导动态核极化［J］. 波谱学杂志, 1995,12(5): 483-494.

［12］Schaublin S, Wokaun A, Ernst R R. Pulse Techniques Applied to Chemically Induced Dynamic Nuclear Polarization［J］. Journal of Magnetic resonance, 1977, 27: 273-302.［13］Gust Devens, Moore Thomas A, Moore Ana L, et al. Proton-Assisted Photoinduced Electron Transfer from Porphyrin to Quinone: A Photo-CIDNP and Laser Flash Photolysis Study［J］. J Phys Chem, 1991, 95: 4442-4445.

［14］王颖，孙建，王鹏，等. 某些卟啉醌模型体系中光诱导氢转移反应机理探索［J］. 波谱学杂志，2001, 18(2): 129-134.

［15］Kazuhiro Maruyama, Hiroyuki Furuta, Atsuhiro Osuka. Cidnp study on porphyrin-photosensitized reactions with phenol and quinone［J］. Tetrahcdron, 1986, 42(22): 6149-6155.

［16］Wegner Mathias, Fischer Hanns, Koeberg Mattijs, et al. Time-resolved CIDNP from photochemically generated radical ion pairs in rigid bichromophoric systems［J］. Chemical Physics, 1999, 242: 227-234.

［17］Erik Schaffner, Hanns fischer. Singlet and Triplet State Back Electron Transfer from Photogenerated Radical Ion Pairs Studied by Time-Resolved CIDNP［J］. J Phys Chem, 1996,100:1657-1665.

［18］Batchelor S N, Fischer H. Time-Resolved CIDNP Investigation of the Cross-Relaxation Mechanism of 1H Nuclear Polarization［J］. J Phys Chem, 1996, 100: 556-564.

［19］Fischer Hanns, Gary P Laroff. Transient and Stationary Nutations in Chemically Induced Dynamic Nuclear Polarzation［J］. Chem Phys, 1974, 3: 217-227.

［20］Tsentalovich Yuri P, Morozova Olga B. Laser flash photolysis and time resolved CIDNP study of photoreaction of 2,2'-dipyridyl with N-acetyl tyrosine in aqueous solutions［J］. Journal of Photochemistry and Photobiology A: Chemistry, 2000, 131: 33-40.

［21］Schaffner Erik, Fischer Hanns. Electron Transfer to Triplet C60 and Subsequent Radical Ion Reactions Studied by Time-Resolved CIDNP［J］. J Phys Chem, 1993,97:13149-13151.

［22］Laufer M, Dreeskamp H. The CIDNP-Detected Laser-Flash photolysis of Benzyl Ketones［J］. J Magn Reson, 1984,60:357-365.

［23］Closs G L, Miller R J. Laser Flash Photolysis with NMR Detection［J］. Submicrosecond Time-Resolved CIDNP: Kinetics of Triplet States and Biradicals. J Am Chem Soc, 1981,103:3586-3588.

［24］Parnachev Andrei, Purtov Peter, Bagryanskaya Elena, et al. Theoretical and experimental studies of CIDNP kinetics in recombination of radical pairs by the method of switched external magnetic field［J］. J Chem Phys, 1997, 107(23): 9942-9953.

［25］Fedin M V, Bagryaniskaya E G, Purtov P A. Theoretical and experimental studies of chemically induced dynamic nuclear polarization kinetics in recombination of radical pairs by the method of switched external magnetic field II. ¹³C CIDNP of micellized radical pairs［J］. J Chem Phys, 1999, 111(12): 5491-5502.

［26］Makarov T N, Bagryanskaya E G, Shakirov S R, et al. CIDNP in a double switched magnetic field［J］. Chemical Physics Letters, 2000, 317:252-259.

［27］Lukzen N N, Morozov V A, Sagdeev R Z. Radical polarization in double switching of external magnetic field［J］. Chem Phys, 1999,241:193-202.

［28］Lyon Charles E, Jones Jonathan A. Redfield Christina, et al. Two-Dimensional ¹⁵N-¹H Photo-CIDNP as a Surface Probe of Native and Partially Structured Proteins［J］. J Am Chem Soc, 1999,121:6505-6506.

[1]	汪红志, 王申林, 胡炳文, 余亦华, 宋一桥, 姚叶锋. 基于数值计算模拟的仿真核磁共振波谱仪开发[J]. 波谱学杂志, 2019, 36(3): 288-297.
[2]	刘文卿, 宋艳红, 王雪璐, 姚叶锋. 光催化甲醇重整机理的原位核磁共振研究[J]. 波谱学杂志, 2019, 36(3): 298-308.
[3]	刘志军, 杨栋, 邵继喜, 胡耀青. 基于低场核磁共振的抚顺油页岩孔隙连通性演化研究[J]. 波谱学杂志, 2019, 36(3): 309-318.
[4]	尹田鹏, 王雅溶, 王敏, 石文智, 张正茜, 何莎莎. 三个C₁₉-二萜生物碱的NMR数据全归属[J]. 波谱学杂志, 2019, 36(3): 331-340.
[5]	杨云汉, 杜瑶, 应飞祥, 杨俊丽, 夏大真, 夏福婷, 杨丽娟. 柚皮素/β-环糊精超分子体系的包合行为[J]. 波谱学杂志, 2019, 36(3): 319-330.
[6]	胡坤, 孙汉董, 普诺·白玛丹增. 量子化学计算核磁共振参数在天然产物结构鉴定中的应用[J]. 波谱学杂志, 2019, 36(3): 359-376.
[7]	王亚兰, 王晓静, 王志伟. 阿齐沙坦的波谱学数据及结构确证[J]. 波谱学杂志, 2019, 36(3): 350-358.
[8]	万至彬, 宋建会, 郭鸣明. 原位液体核磁共振在高分子材料表征领域的应用[J]. 波谱学杂志, 2019, 36(3): 408-424.
[9]	唐明学, SCHMIDT Claudia. 利用核磁共振氢谱的哈勒分析获得分子序列取向参数[J]. 波谱学杂志, 2019, 36(2): 138-147.
[10]	曹园, 吴永平, 陈东军. 卷柏属Selaginellin类化合物互变异构的波谱学研究[J]. 波谱学杂志, 2019, 36(2): 155-163.
[11]	汤衡, Gilbert NSHOGOZA, 刘明清, 刘亚茜, 阮科, 马荣声, 高佳. 基于片段的核磁共振筛选方法识别NSD1 SET结构域的全新苗头化合物[J]. 波谱学杂志, 2019, 36(2): 148-154.
[12]	肖雄杰, HU Mary, 张许, HU Jian-zhi. 电离辐射对小鼠肾脏影响的代谢组学研究[J]. 波谱学杂志, 2019, 36(2): 172-181.
[13]	徐小俊, 王申林. ¹⁹F固体核磁共振技术研究膜蛋白相互作用的进展[J]. 波谱学杂志, 2019, 36(2): 238-251.
[14]	寇新慧, 刘乙祥, 刘兴弘, 李从刚, 刘买利, 姜凌. 探测应答调控蛋白PhoB_N^F20D自由态中存在的Pre-Active构象[J]. 波谱学杂志, 2019, 36(2): 164-171.
[15]	陈晓瑛, 俞刚金, 毛诗珍, 刘买利, 杜有如. 利用¹H NMR探究混合离子型/非离子型表面活性剂临界胶束浓度降低的实质[J]. 波谱学杂志, 2019, 36(2): 219-224.