核磁共振氢谱法鉴定油性圆珠笔文书的书写时间

doi:10.11938/cjmr20160203

波谱学杂志 ›› 2016, Vol. 33 ›› Issue (2): 198-207.doi: 10.11938/cjmr20160203

核磁共振氢谱法鉴定油性圆珠笔文书的书写时间

郑津, 薛惠芸, 林彩凤, 林德洵, 陆嘉, 杨慧, 王相鹏, 邹友思

厦门大学材料学院, 福建厦门 361005

收稿日期:2015-06-01 修回日期:2016-04-18 出版日期:2016-06-05 发布日期:2016-06-05
通讯作者: 邹友思,电话:13860136496,E-mail:yszou@xmu.edu.cn. E-mail:yszou@xmu.edu.cn
作者简介:郑津(1990-),福建福州人,硕士研究生,高分子化学与物理专业.

Dating Oily Ballpoint Pen Hand-Writings by ¹H NMR Spectroscopy

ZHENG Jin, XUE Hui-yun, LIN Cai-feng, LIN De-xun, LU Jia, YANG Hui, WANG Xiang-peng, ZOU You-si

College of Materials, Xiamen University, Xiamen 361005, China

Received:2015-06-01 Revised:2016-04-18 Online:2016-06-05 Published:2016-06-05

摘要/Abstract

摘要：

油性圆珠笔文书书写时间的鉴定是司法鉴定工作中的热点.该文采用核磁共振氢谱法(¹H NMR)对所购6种不同型号油性圆珠笔的油墨进行了表征,研究了圆珠笔油墨中的溶剂——苯氧基乙醇在文书老化过程中的变化,并建立了MG-115书写文书的自然老化标准曲线.该标准曲线能够准确鉴定MG-115圆珠笔4个月内的文书书写时间,重现性良好;同时,该文探究了人工老化与自然老化的关系,为文书书写时间的鉴定提供了依据.

关键词: 油性圆珠笔, 书写时间, 核磁共振氢谱法(¹H NMR), 苯氧基乙醇

Abstract:

Dating ballpoint pen hand-writings is a hot topic in forensic science. It remains untested whether NMR spectroscopy is suitable for this task. In this study, six types of oily ballpoint pen ink were characterized by ¹H NMR spectroscopy. The same method was also used to measure the changes of 2-phenoxyethanol content in oily ballpoint pen hand-writings with aging. A standard curve was established based on the experimental results. It was demonstrated that, as long as the brand of the oily ballpoint pen used was known, hand-writings made within 4 months could be dated precisely. The effects of artificial aging and natural aging were compared subsequently. It was found that ten minutes in ultraviolet aging box corresponded to approximately one day of natural aging.

Key words: oily ballpoint pen, writing time, ¹H NMR, 2-phenoxyethanol

中图分类号:

O482.53

郑津, 薛惠芸, 林彩凤, 林德洵, 陆嘉, 杨慧, 王相鹏, 邹友思. 核磁共振氢谱法鉴定油性圆珠笔文书的书写时间[J]. 波谱学杂志, 2016, 33(2): 198-207.

ZHENG Jin, XUE Hui-yun, LIN Cai-feng, LIN De-xun, LU Jia, YANG Hui, WANG Xiang-peng, ZOU You-si. Dating Oily Ballpoint Pen Hand-Writings by ¹H NMR Spectroscopy[J]. Chinese Journal of Magnetic Resonance, 2016, 33(2): 198-207.

参考文献

[1] Zhang Jing(张晶), Xie Peng(谢朋), Cui Lan(崔岚). Research status of identifying the writing age of ballpoint inks(圆珠笔油墨形成时间鉴定的研究现状)[J]. Journal of Chinese People's Public Security University (Science and Technology)[中国人民公安大学学报(自然科学版)], 2004, 4(4):56-60.

[2] LuoYi-wen(罗仪文), Xu Che(徐彻), Yang Xu(杨旭). An evaluation of ballpoint ink dating techniques(油性圆珠笔字迹书写时间鉴定的研究综述)[J]. Chinese Journal of Forensic Sciences(中国司法鉴定), 2007, 4(3):33-36.

[3] Alimjan Abdura(阿里木江·艾拜都拉). An Study of Identifying the Type of Ballpoint Inks by Chromatography(色谱法对笔中油墨种类鉴别的研究)[D]. Beijing(北京):Capital Normal University(首都师范大学), 2005.

[4] Brunelle R L, Breedlove C H, Midkiff C R. Determining the relative age of ballpoint inks using a single-solvent extraction technique[J]. J Forensic Sci, 1987, 32(6):1511-1521.

[5] Aginsky V. Determination of the age of ballpoint pen ink by gas and densitometric thin-layer chromatography[J]. J Chromatogr A, 1994, 678(1):119-125.

[6] Andrasko J. HPLC analysis of ballpoint pen inks stored at different light conditions[J]. J Forensic Sci, 2001, 46(1):21-30.

[7] Weyermann C, Marquis R, Mazzella W, et al. Differentiation of blue ballpoint pen inks by laser desorption ionization mass spectrometry and high-performance thin-layer chromatography[J]. J Forensic Sci, 2007, 52(1):216-220.

[8] Bügler J, Buchner H, Dallmayer A. Age determination of ballpoint pen ink by thermal desorption and gas chromatography-mass spectrometry[J]. J Forensic Sci, 2008, 53(4):982-988.

[9] Weyermann C, Kirsch D, Vera C C, et al. Evaluation of the photodegradation of crystal violet upon light exposure by mass spectrometric and spectroscopic methods[J]. J Forensic Sci, 2009, 54(2):339-345.

[10] Silva C S, Pimentel M F, Honorato R S, et al. Near infrared hyperspectral imaging for forensic analysis of document forgery[J]. Analyst, 2014, 139(20):5176-5184.

[11] Ferreira P D, Silva D F A E, Augusti R, et al. Forensic analysis of ballpoint pen inks using paper spray mass spectrometry[J]. Analyst, 2015, 140(3):811-819.

[12] Li Ji-min(李继民), Wang Yan(王岩), Zhao Yan-jun(赵彦军), et al. Study on volatile components in blue ballpoint inks(蓝色圆珠笔油墨色痕中挥发成分的研究)[J]. Journal of Chinese People's Public Security University (Science and Technology)[中国人民公安大学学报(自然科学版)], 2004, 4(4):13-16.

[13] Wang Yan(王岩), Yao Li-juan(姚丽娟), Zhao Peng-cheng(赵鹏程), et al. Determination of the writing age of blue ballpoint ink by gas chromatography(气相色谱法确定蓝色圆珠笔油墨字迹的形成时间)[J]. Chinese Journal of Chromatography(色谱), 2005, 23(2):202-204.

[14] Weyermann C, Kirsch D, Vera C C, et al. A GC/MS study of the drying of ballpoint pen ink on paper[J]. Forensic Sci Int, 2007, 168(2, 3):119-127.

[15] Berger-Karin C, Hendriks U, Geyer-Lippmann J. Comparison of natural and artificial aging of ballpoint inks[J]. J Forensic Sci, 2008, 53(4):989-992.

[16] Weyermann C, Almog J, Bügler J, et al. Minimum requirements for application of ink dating methods based on solvent analysis in casework[J]. Forensic Sci Int, 2011, 210(1, 2, 3):52-62.

[17] Li Chun-fa(李春发), Zhu Xue-rong(朱雪荣). An NMR and FT-IR study on polyether modified silicon surfactant(聚醚改性有机硅表面活性剂的核磁共振及红外光谱表征)[J]. Chinese J Magn Reson(波谱学杂志), 2014, 31(2):222-231.

[18] Yang Ying-wen(杨应文), Wang Ya-li(王亚丽), Sa Ri-na(萨日娜), et al. Chemical fingerprinting of Angelica sinensis at different growth stages by ¹H NMR(不同生长期当归¹H NMR指纹图谱的研究)[J]. Chinese J Magn Reson(波谱学杂志), 2013, 30(1):69-79.

核磁共振氢谱法鉴定油性圆珠笔文书的书写时间

Dating Oily Ballpoint Pen Hand-Writings by ¹H NMR Spectroscopy

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

PSSS₅₀-b-PNIPAM₃₀₀嵌段共聚物在二元溶剂中自组装的NMR研究

编辑推荐

Metrics

本文评价

[1]	赵尚义王远军. 基于磁共振图像和改进的UNet++模型区分阿尔茨海默症患者和健康人群[J]. 波谱学杂志, 0, (): 0-0.
[2]	鲁晨董健健钟凯. 9.4T下TX模型鼠脑DTI成像研究[J]. 波谱学杂志, 0, (): 0-0.
[3]	王可张英华李雨晴邹定华. 固体核磁共振技术在水泥基材料研究中的应用[J]. 波谱学杂志, 0, (): 0-0.
[4]	刘可文刘紫龙汪香玉陈黎李钊吴光耀刘朝阳. 基于级联卷积神经网络的前列腺磁共振图像分类[J]. 波谱学杂志, 0, (): 0-0.
[5]	闫松屠小青彭梅. 光泵抽运³He极化程度监控系统的设计与实现[J]. 波谱学杂志, 0, (): 0-0.
[6]	张一鸣陈志雪杨晓云. 丁氟螨酯的波谱学数据解析与结构确证[J]. 波谱学杂志, 0, (): 0-0.
[7]	王强魏树峰王铮杨文晖. 基于粒子群与遗传算法的矩阵式梯度线圈优化设计[J]. 波谱学杂志, 0, (): 0-0.
[8]	王佳鑫冯继文陈俊飞王立英刘朝阳. 魔角旋转固体核磁共振探头中转子的研制[J]. 波谱学杂志, 0, (): 0-0.
[9]	赵智慧刘表兰闫小双武帅帅茹阁英毛诗珍冯继文. PSSS₅₀-b-PNIPAM₃₀₀嵌段共聚物在二元溶剂中自组装的NMR研究 [J]. 波谱学杂志, 0, (): 0-0.
[10]	刘慧霞, 辛家祥, 魏达秀. 核自旋单重态的制备及其转化效率和寿命的影响因素分析 [J]. 波谱学杂志, 0, (): 0-0.
[11]	雷振宇, 梁欣苗#, 雷友义, 杨丽, 冯继文. 固体核磁共振技术在锂/钠离子电池碳负极中的应用及研究进展 [J]. 波谱学杂志, 0, (): 0-0.
[12]	张之杰李端秀罗春仇汝臣邓宗武张海禄. 晶体学辅助的2-吡啶甲酸固体13C化学位移理论计算归属[J]. 波谱学杂志, 0, (): 0-0.
[13]	包婉静曾庆琦余钫秦蕾陈智勇. 一种非连续微波探询信号的实现[J]. 波谱学杂志, 0, (): 0-0.
[14]	张芬芬沈文斌徐开兵杨明. 基于定量核磁共振氢谱测定新药替格瑞洛[J]. 波谱学杂志, 0, (): 0-0.
[15]	徐广永董满园马建锋张利民. 固体核磁共振研究半晶聚-3-羟基丁酸酯和聚羟基丁酸戊酸酯的分子动力学（英文） [J]. 波谱学杂志, 0, (): 0-0.

核磁共振氢谱法鉴定油性圆珠笔文书的书写时间

Dating Oily Ballpoint Pen Hand-Writings by 1H NMR Spectroscopy

PDF

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

PSSS50-b-PNIPAM300嵌段共聚物在二元溶剂中自组装的NMR研究

编辑推荐

Metrics

本文评价

Dating Oily Ballpoint Pen Hand-Writings by ¹H NMR Spectroscopy

PSSS₅₀-b-PNIPAM₃₀₀嵌段共聚物在二元溶剂中自组装的NMR研究