Chinese Journal of Magnetic Resonance ›› 2021, Vol. 38 ›› Issue (3): 291-300.doi: 10.11938/cjmr20212888
• Articles • Previous Articles Next Articles
Xiao-li CHEN1,2,Tian-qiao YONG3,Cheng CHEN1,2,Juan FU1,2,Jia-mei MO1,2,Qiu-cheng SU1,2,*()
Received:
2021-02-08
Online:
2021-09-05
Published:
2021-04-08
Contact:
Qiu-cheng SU
E-mail:suqc@ms.giec.ac.cn
CLC Number:
Xiao-li CHEN,Tian-qiao YONG,Cheng CHEN,Juan FU,Jia-mei MO,Qiu-cheng SU. Physical and Chemical Properties of Silicone Electrolyte Materials Evaluated by Nuclear Magnetic Resonance Technology[J]. Chinese Journal of Magnetic Resonance, 2021, 38(3): 291-300.
Table 1
13C NMR chemical shifts of various groups of BNS in electrolytes with different molar concentrations of LiPF6
LiPF6/BNS (mol/L) | δC | ||||||
-CN | -CH2O- | -SiOCH2- | CH3O- | NCCH2- | -SiCH2- | -SiCH3 | |
0 | 121.27 | 73.78 | 62.24 | 58.37 | 10.71 | 10.54 | -5.04 |
0.25 | 121.46 | 73.74 | 62.23 | 58.38 | 10.61 | 10.51 | -5.08 |
0.50 | 121.60 | 73.67 | 62.19 | 58.38 | 10.47 | 10.47 | -5.12 |
0.75 | 121.68 | 73.61 | 62.15 | 58.36 | 10.41 | 10.36 | -5.19 |
1.00 | 121.81 | 73.55 | 62.12 | 58.37 | 10.37 | 10.22 | -5.26 |
1 | LI X Z , SU F , XU Y L . Research progress of materials for power lithium-ion battery[J]. Chin Bat Ind, 2018, 22 (003): 138- 146. |
李相哲, 苏芳, 徐烨玲. 锂离子动力电池材料研究进展[J]. 电池工业, 2018, 22 (003): 138- 146. | |
2 | KALHOFF J , BRESSER D , BOLLOLI M , et al. Enabling LiTFSI-based electrolytes for safer lithium-ion batteries by using linear fluorinated carbonates as (Co) solvent[J]. Chemsuschem, 2015, 7 (10): 2939- 2946. |
3 |
IMAE I , KATAOKA H , HARIMA Y . Flexible thermoelectric materials based on conducting polymers doped with silicone polymer electrolyte[J]. Molecular Crystals and Liquid Crystals, 2019, 685 (1): 100- 106.
doi: 10.1080/15421406.2019.1645467 |
4 |
KIM S Y , KIM C H , YANG C M . Binder-free silicon anodes wrapped in multiple graphene shells for high-performance lithium-ion batteries[J]. Journal of Power Sources, 2021, 486, 229350.
doi: 10.1016/j.jpowsour.2020.229350 |
5 | WU W , QIN W , HE H , et al. Synthesis of cyano containing organosilicon based electrolytes[J]. Silicone Material, 2017, 31 (5): 339- 343. |
吴伟, 秦文, 何海, 等. 含氰基有机硅电解质的合成[J]. 有机硅材料, 2017, 31 (5): 339- 343. | |
6 |
KIM K M , LY N V , WON J H , et al. Improvement of lithium-ion battery performance at low temperatureby adopting polydimethylsiloxane- based electrolyte additives[J]. Electrochimica Acta, 2014, 136, 182- 188.
doi: 10.1016/j.electacta.2014.05.054 |
7 | ZHAO X Y , WANG J L , YAN X D , et al. Effect of nitrile group functionalized organosilicon as electrolyte additive on low-temperature performance of LiFePO4battery[J]. Chemical Journal of Chinese Universities, 2019, 40 (6): 1258- 1264. |
赵欣悦, 汪精伦, 闫晓丹, 等. 腈基功能化有机硅电解液添加剂对LiFePO4电池低温性能的影响[J]. 高等学校化学学报, 2019, 40 (6): 1258- 1264. | |
8 |
LI Y J , LI Y J , WU F , et al. The progress in exploration of organosiloxane used in the electrolyte to improve the lithium batteries' safety performance[J]. Journal of Functional Materials, 2014, 45 (22): 22001- 22005.
doi: 10.3969/j.issn.1001-9731.2014.22.001 |
李月姣, 李雅静, 吴锋, 等. 有机硅在锂离子电池电解质中的应用[J]. 功能材料, 2014, 45 (22): 22001- 22005.
doi: 10.3969/j.issn.1001-9731.2014.22.001 |
|
9 | YANG K , SHUAI X R , YANG H C , et al. Electrochemical performance of activated graphene powder supercapacitors using a room temperature ionic liquid electrolyte[J]. Acta Physico-Chimica Sinica, 2019, 35 (7): 755- 765. |
杨康, 帅骁睿, 杨化超, 等. 基于室温离子液体的活化石墨烯粉末超级电容储能性能[J]. 物理化学学报, 2019, 35 (7): 755- 765. | |
10 | ZHANG H H , ZHENG W , CHEN Y P . Principle and application of spectroscopy[M]. Beijing: Chemical Industry Press, 2016, 100- 104. |
张汉辉, 郑威, 陈义平. 波谱学原理及应用[M]. 北京: 化学工业出版社, 2016, 100- 104. | |
11 | LEI Z Y , LIANG X M , LEI Y Y , et al. Progresses in solid-state NMR studies on carbon anode materials for lithium/sodium-ion batteries[J]. Chinese J Magn Reson, 2020, 37 (1): 28- 39. |
雷振宇, 梁欣苗, 雷友义, 等. 固体核磁共振技术在锂/钠离子电池碳负极中的应用及研究进展[J]. 波谱学杂志, 2020, 37 (1): 28- 39. | |
12 |
AMUL B , MUTHU S , RAJA M , et al. Molecular structure, spectroscopic (FT-IR, FT-Raman, NMR, UV-VIS), chemical reactivity and biological examinations of ketorolac[J]. J Mol Struc, 2020, 1210, 128040.
doi: 10.1016/j.molstruc.2020.128040 |
13 | WEN L , LI C F . Structure and configuration analyses of a nucleating agent for isotactic polypropylene crystallization[J]. Chinese J Magn Reson, 2020, 37 (3): 291- 299. |
温亮, 李春发. 规聚丙烯成核剂的结构和构型分析[J]. 波谱学杂志, 2020, 37 (3): 291- 299. | |
14 | XU S J , SUN Z H , SUN C G , et al. Homogeneous and fast ion conduction of PEO-based solid-state electrolyte at low temperature[J]. Advanced Functional Materials, 2020, 2007172. |
15 | LI H W , YUAN Z L , XIA B . Determination of apparent protein molecular weight in solution by diffusion ordered NMR spectroscopy[J]. Chinese J Magn Reson, 2018, 35 (3): 280- 286. |
李红卫, 袁志良, 夏斌. 扩散序谱(DOSY)实验测定缓冲体系中蛋白质表观分子量[J]. 波谱学杂志, 2018, 35 (3): 280- 286. | |
16 |
ZHANG P , CHEN Y , LUO W . Application progress of nuclear magnetic resonance diffusion ordered spectroscopy[J]. Journal of Instrumental Analysis, 2020, 39 (8): 1050- 1057.
doi: 10.3969/j.issn.1004-4957.2020.08.017 |
张鹏, 陈媛, 罗维. 核磁共振扩散序谱的研究及应用进展[J]. 分析测试学报, 2020, 39 (8): 1050- 1057.
doi: 10.3969/j.issn.1004-4957.2020.08.017 |
|
17 |
YAN X D , ZHANG L Z , LU J D . Improve safety of high energy density LiNi1/3Co1/3Mn1/3O2/graphite battery using organosilicon electrolyte[J]. Electrochimica Acta, 2019, 296, 149- 154.
doi: 10.1016/j.electacta.2018.11.036 |
18 |
YONG T Q , WANG J L , MAI Y J , et al. Organosilicon compounds containing nitrile and oligo(ethylene oxide) substituents as safe electrolytes for high-voltage lithium-ion batteries[J]. Journal of Power Sources, 2014, 254, 29- 32.
doi: 10.1016/j.jpowsour.2013.12.087 |
19 | 雍天乔. 新型锂离子电池电解液材料及其安全高电压性能的研究[D]. 广州: 中国科学院大学广州能源研究所, 2014, 31-32. |
20 |
XUAN X P , ZHANG H C , WANG J J , et al. Spectroscopic study of ion-solvent and ion-ion interactions in lithium battery electrolyte solution Ⅶ. LiBF4/g-butyrolactone[J]. Journal of Henan Normal University (Natural Science), 2002, 30 (4): 126.
doi: 10.3969/j.issn.1000-2367.2002.04.036 |
轩小朋, 张虎成, 王键吉, 等. 锂电池电解质溶液中离子-溶剂和离子-离子相互作用的谱学研究Ⅶ. LiBF4/g-丁内酯[J]. 河南师范大学学报(自然科学版), 2002, 30 (4): 126.
doi: 10.3969/j.issn.1000-2367.2002.04.036 |
|
21 | WANG J L , YAN X D , YONG T Q , et al. Nitrile-modified 2, 5-di-tert-butyl-hydroquinones as redox shuttle overcharge additives for lithium-ion batteries[J]. Acta Physico-Chimica Sinica, 2016, 32 (9): 2293- 2300. |
汪精伦, 闫晓丹, 雍天乔, 等. 过充保护添加剂氰基功能化2, 5-二叔丁基对苯二酚的合成及其在锂离子电池中的应用[J]. 物理化学学报, 2016, 32 (9): 2293- 2300. | |
22 | HUANG J L , YU Y H . Effects of digital resolution on diffusional dimension in DOSY experiments[J]. Chinese J Magn Reson, 2018, 35 (3): 287- 293. |
黄俊霖, 余亦华. 扩散序谱(DOSY)实验中扩散系数维数字分辨率的影响[J]. 波谱学杂志, 2018, 35 (3): 287- 293. | |
23 |
ARAVINDAN V , GNANARAJ J , MADHAVI S , et al. Lithium-ion conducting electrolyte salts for lithium batteries[J]. Chemistry, 2011, 17 (51): 14326- 14346.
doi: 10.1002/chem.201101486 |
24 |
ZHAO H , YUAN L , JI L K , et al. Study of lithium hexafluorophosphate by NMR spectroscopy[J]. Guangzhou Chemical Industry, 2014, 42 (14): 106- 108, 119.
doi: 10.3969/j.issn.1001-9677.2014.14.037 |
赵洪, 袁莉, 纪烈孔, 等. 六氟磷酸锂的核磁共振波谱研究[J]. 广州化工, 2014, 42 (14): 106- 108, 119.
doi: 10.3969/j.issn.1001-9677.2014.14.037 |
[1] | Lei JIANG,Yang FU,Wen-wen GUO,Guo ZHENG,Qiang WANG. Nuclear Magnetic Resonance Assignment and Crystal Structure of 3, 22-Dihydroxyhopane [J]. Chinese Journal of Magnetic Resonance, 2021, 38(2): 255-267. |
[2] | Meng-yu DOU,Qi ZHAO,Xiang-lin HOU,Lei LIU,Ming-xing TANG,Ying-xiong WANG. Structural Elucidation and Quantitative Analysis of Hydrogenation Products of Anthracene by NMR Spectroscopy [J]. Chinese Journal of Magnetic Resonance, 2021, 38(2): 239-248. |
[3] | Xiao-li CHEN,Wei LV,Qiu-cheng SU,Juan FU,Jia-mei MO,Qi-ying LIU. Conversion of Lignocellulose Studied by Nuclear Magnetic Resonance [J]. Chinese Journal of Magnetic Resonance, 2021, 38(2): 277-290. |
[4] | ZHANG Fen-fen, SHEN Wen-bin, XU Kai-bing, YANG Ming. A Proton Nuclear Magnetic Resonance Method for Quantitative Analysis of Ticagrelor [J]. Chinese Journal of Magnetic Resonance, 2020, 37(2): 216-223. |
[5] | TANG Ming-xue, SCHMIDT Claudia. Estimation of Nematic Order Parameters via Haller Analysis of 1H NMR Spectra of Liquid Crystals [J]. Chinese Journal of Magnetic Resonance, 2019, 36(2): 138-147. |
[6] | XIAO Xiong-jie, HU Mary, ZHANG Xu, HU Jian-zhi. An NMR-Based Metabolomics Study of Kidneys from Mice Exposed to Ionizing Radiation [J]. Chinese Journal of Magnetic Resonance, 2019, 36(2): 172-181. |
[7] | WANG Shuang-hong, ZENG Pei, PAN Si-na, WANG Jia, WANG Shu-mei, YANG Yong-xia. Effects of Gegen Qinlian Decoction on the Fecal Metabonome of High Fructose-Induced Insulin Resistance Rats Studied by 1H NMR Spectroscopy [J]. Chinese Journal of Magnetic Resonance, 2019, 36(2): 182-194. |
[8] | WU Jin-ze, XIN Jia-xiang, FU Xiao-bin, YAO Ye-feng. A Wide-Line Solid-State 1H NMR Study of Phase Structures of Semi-Crystalline Polymers [J]. Chinese Journal of Magnetic Resonance, 2019, 36(1): 23-33. |
[9] | WU Ya-xin, CAO Chen-zhong, TENG Li-li. Estimation of Formation Enthalpy for Alkanes from 13C NMR Chemical Shifts [J]. Chinese Journal of Magnetic Resonance, 2019, 36(1): 65-73. |
[10] | LI Hong-wei, YUAN Zhi-liang, XIA Bin. Determination of Apparent Protein Molecular Weight in Solution by Diffusion Ordered NMR Spectroscopy [J]. Chinese Journal of Magnetic Resonance, 2018, 35(3): 280-286. |
[11] | HUANG Jun-lin, YU Yi-hua. Effects of Digital Resolution on Diffusional Dimension in DOSY Experiments [J]. Chinese Journal of Magnetic Resonance, 2018, 35(3): 287-293. |
[12] | ZHAO Hong-bo, CHAI Xiao-fei, WANG Yue-hua, SHI Hui-bing, ZHANG Rui, DONG Zhao-ping, HAN Li-xia. Analysis of Styrene-Butadiene-Styrene (SBS) Content in Modified Asphalt with 1H NMR Spectroscopy [J]. Chinese Journal of Magnetic Resonance, 2017, 34(3): 323-328. |
[13] | FU Juan, WU Neng-you, WU Dai-dai, SU Qiu-cheng. A Solid-State 13C NMR and Laser Raman Spectroscopy Study on Synthesized Methane Hydrates [J]. Chinese Journal of Magnetic Resonance, 2017, 34(2): 148-155. |
[14] | CAO Chao-tun, LUO Qing-qing, CAO Chen-zhong. Substituent Effects on the 1H NMR Chemical Shifts of CH=N(O) Bridge Group in Diaryl Nitrone [J]. Chinese Journal of Magnetic Resonance, 2017, 34(1): 69-77. |
[15] | WANG Li-min, QIU Ru-chen, HUANG Shao-hua. Quantitative Analysis of Active Ingredients in Compound Acetylsalicylic Acid Tablets by DOSY [J]. Chinese Journal of Magnetic Resonance, 2016, 33(3): 415-421. |
Viewed | ||||||
Full text |
|
|||||
Abstract |
|
|||||