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ESR和NMR在茂金属催化剂和聚烯烃研究中的应用

王文钦,王立*, 王剑峰,马振利   

  1. 浙江大学高分子科学与工程学系,浙江杭州 310027
  • 收稿日期:2002-11-18 修回日期:2002-12-30 出版日期:2003-06-05 发布日期:2003-06-05
  • 作者简介:*通讯联系人: Tel:0571-87952400
  • 基金资助:

    National Natural Science Foundation of China (20172045, 20174032).

APPLICATION OF ESR AND NMR TO INVESTIGATION OF METALLOCENE CATALYST AND POLYOLEFIN

WANG Wen-qin, WANG Li*, WANG Jian-feng, MA Zhen-li   

  1. Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
  • Received:2002-11-18 Revised:2002-12-30 Online:2003-06-05 Published:2003-06-05
  • About author:Wang Wen-qin(1974-),male,WeiFang of Shandong.Now he is starting his Ph.D.working in the Department of Polymer Science and Engineering of Zhejiang University. The research area of his Ph.D.is the polymer supported metallocene catalyst for olefin polymerization. *Correspondence author: Tel:0571-87952400
  • Supported by:

    National Natural Science Foundation of China (20172045, 20174032).

摘要:

随着高分子科学和催化技术的发展,了解聚合物和催化剂的微结构信息尤为重要. 主要介绍了ESR和NMR在茂金属催化剂和聚烯烃领域中的最新应用,研究成果表明ESR和NMR是研究聚合物和催化剂微观信息的有效工具.

关键词: ESR, NMR, 茂金属, 聚烯烃, 微结构信息

Abstract:

With the rapid development of polymer science and catalysis technology, it has become more and more important to understand the microstructures of polymer and catalyst. In the paper, the recent applications of ESR and NMR in studying metallocene catalyst and polyolefin are reviewed. The results suggest that the ESR and NMR techniques useful research tools in studying the microstructure of polymers and catalysts.

Key words: ESR, NMR, metallocene, polyolefin, microstructure information

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