波谱学杂志 ›› 2001, Vol. 18 ›› Issue (4): 391-395.

• 研究简报 • 上一篇    下一篇

N-(2-苯基-1,2,3-连三唑-4-甲酰基)-N′-芳基硫脲的13C NMR谱的研究

许永廷1,胡皆汉3,李英俊2,杨晓南2,王光明2   

  1. 辽宁师范大学 1.实验中心,2.化学系,大连 116029;3.中国科学院大连 化学物理研究所,大连 116023
  • 收稿日期:2001-07-23 修回日期:2001-09-03 出版日期:2001-12-05 发布日期:2001-12-05
  • 作者简介:许永廷(1958-),男,高级实验师.
  • 基金资助:

    辽宁省教委科研基金资助项目(No.9802211056).

13C NMR STUDY OF N-(2-PHENYL-1,2,3-TRIAZOLE-4-ACTYL)-N′-ARYLTHIOUREAS

XU Yong-ting1,HU Jie-han3,LI Ying-jun2, YANG Xiao-nan2,WANG Guang-ming2   

  1. 1Centre of Experiment,2.Department of Chemistry,Liaoning Normal University, Dalian 116029;3.Dalian Institute of Chemical Physics,The Chinese Academy of Sciences,Dal ian 116023
  • Received:2001-07-23 Revised:2001-09-03 Online:2001-12-05 Published:2001-12-05
  • Supported by:

    辽宁省教委科研基金资助项目(No.9802211056).

摘要:

研究了最近合成的6种N-(2-苯基-1,2,3-连三唑-4-甲酰基)-N′-芳基硫脲新化合物. 通过测定6种新化合物的13C NMR和DEPT谱等,对其结构进行了确定,并对其 全部谱峰做出归属;并给出了这类新化合物中苯的两个新取代基(R1R2 )的取代参数;同时,讨论了化学位移与分子结构间的一些关系. 

关键词: N-(2-苯基-1,2,3-连三唑-4-甲酰基)-N′-芳基硫脲,  13C NM R谱, 化学位移, 分子结构, 取代参数

Abstract:

13C NMR spectra of 6 new kinds of N-(2-phenyl-1,2,3-triazole-4-actyl)- N′-Arylt hioureas are reported in this paper. These compounds will have potential applica tion value for the use  as plant growth regulators,antitumor medicine or ch emical picki ng agent for fruits. By testing the 13C NMR spectra, the structures have been d etermined and all 13C NMR peaks have been assigned. The effects of str ucture on  the chemical shifts are discussed. At the same time, the subtituent parameters o f the two new substituent (R1 and R2) are given.

Key words: N-(2-phenyl-1,2,3-triazole-4-actyl)-N′-Arylthioureas,  13C NMR, Chemical shift, Molecular structure

中图分类号: