固体核磁共振研究单斜磷酸钒锂的进展(英文)

doi:10.11938/cjmr20192782

波谱学杂志 ›› 2020, Vol. 37 ›› Issue (1): 16-27.doi: 10.11938/cjmr20192782

固体核磁共振研究单斜磷酸钒锂的进展(英文)

林泽羽, 霍华, 王启航

新能源储存与转化关键材料技术工信部重点实验室, 化工与化学学院, 哈尔滨工业大学, 黑龙江哈尔滨 150001

收稿日期:2019-09-17 出版日期:2020-03-05 发布日期:2019-11-07
通讯作者: 霍华,Tel:0451-86413721,E-mail:huohua@hit.edu.cn. E-mail:huohua@hit.edu.cn
基金资助:
the National Natural Science Foundation of China (21673065, 21403045, 21573013, 91745202)

Progress in Solid-State NMR Studies of Monoclinic Lithium Vanadium Phosphate

LIN Ze-yu, HUO Hua, WANG Qi-hang

MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China

Received:2019-09-17 Online:2020-03-05 Published:2019-11-07
Supported by:
the National Natural Science Foundation of China (21673065, 21403045, 21573013, 91745202)

摘要/Abstract

摘要： 在过去的二十年里，单斜型磷酸钒锂作为一种有前景的锂离子电池正极材料被广泛研究.固体核磁共振技术是一种研究原子局部环境和运动性，并能反映材料中长程/短程有序结构变化的有力表征手段，可以从多个角度满足磷酸钒锂材料的研究需求.本文从充放电机理、锂离子的迁移率和动力学、碳包覆、阳离子掺杂等方面简要介绍了固体核磁共振技术在单斜磷酸钒锂正极材料研究中的应用，同时涵盖了相关的理论计算工作.

关键词: 固体核磁共振, 锂离子电池, 正极材料, 综述, 磷酸钒锂

Abstract: Monoclinic lithium vanadium phosphate is a promising cathode material for lithium-ion batteries, which has been widely studied in the past two decades. Solid-state nuclear magnetic resonance (SSNMR) is an excellent method to investigate the local environments of target nuclei and the short/long range structural changes of materials. In this short review, SSNMR studies on a few important aspects of monoclinic lithium vanadium phosphate, including charge-discharge mechanism, lithium mobility/dynamics, carbon coating, cation doping and theoretical calculation on NMR shifts, are briefly covered.

Key words: solid-state nuclear magnetic resonance, lithium ion battery, cathode material, review, lithium vanadium phosphate

中图分类号:

O482.53

林泽羽, 霍华, 王启航. 固体核磁共振研究单斜磷酸钒锂的进展(英文)[J]. 波谱学杂志, 2020, 37(1): 16-27.

LIN Ze-yu, HUO Hua, WANG Qi-hang. Progress in Solid-State NMR Studies of Monoclinic Lithium Vanadium Phosphate[J]. Chinese Journal of Magnetic Resonance, 2020, 37(1): 16-27.

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固体核磁共振研究单斜磷酸钒锂的进展(英文)

Progress in Solid-State NMR Studies of Monoclinic Lithium Vanadium Phosphate

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