2,6-双(三甲基锡)-4,8-双(2-乙基己氧基)苯并[1,2-b∶4,5-b´]二噻吩的合成与多核NMR研究

波谱学杂志

2,6-双(三甲基锡)-4,8-双(2-乙基己氧基)苯并[1,2-b∶4,5-b´]二噻吩的合成与多核NMR研究

王民昌*，张皋，徐敏，刘红利，栾洁玉，陈智群，齐珠钗

西安近代化学研究所，陕西西安 710065

收稿日期:2012-03-12 修回日期:2012-04-21 出版日期:2013-06-05 发布日期:2013-06-05
作者简介:王民昌（1980-），男，甘肃岷县人，工程师，主要从事波谱学应用研究. 电话：029-88291664，E-mail：wmc204@163.com.*通讯联系人.
基金资助:
国家自然科学基金资助项目（61177031）.

Synthesis and Multinuclear NMR Study on 2,6-Bis(trimethyltin)-4,8-bis(2-ethylhexyloxy)benzo[1,2-b:4,5-b´]dithiophene

WANG Min-chang*，ZHANG Gao，XU Min，LIU Hong-li，LUAN Jie-yu，CHEN Zhi-qun，QI Zhu-chai

Xi´an Modern Chemistry Research Institute, Xi´an 710065, China

Received:2012-03-12 Revised:2012-04-21 Online:2013-06-05 Published:2013-06-05
About author:*Corresponding author: Wang Min-chang,Tel:029-88291664,E-mail：wmc204@163.com.
Supported by:
国家自然科学基金资助项目（61177031）.

摘要/Abstract

摘要：

以苯并[1,2-b∶4,5-b´]二噻吩-4,8-二酮为原料合成了一种聚合物太阳能电池材料的单体2,6-双(三甲基锡)-4,8-双(2-乙基己氧基)苯并[1,2-b∶4,5-b´]二噻吩. 通过多核1D和2D NMR技术（包括1D ¹H、¹³C、¹¹⁹Sn、¹¹⁷Sn NMR、DEPT、选择性1D TOCSY及2D ¹H-¹H COSY、gHSQC、gHMBC）表征了目标分子结构，完成了 ¹H、¹³C、¹¹⁹Sn 与¹¹⁷Sn NMR化学位移归属，并探讨了该化合物的NMR谱线特征.

关键词: 核磁共振（NMR）, 归属, ¹¹⁹Sn NMR, , 2,6-双(三甲基锡)-4,8-双(2-乙基己氧基)苯并[1,2-b∶4,5-b´]二噻吩, 聚合物太阳能电池

Abstract:

2,6-Bis(trimethyltin)-4,8-bis(2-ethylhexyloxy)benzo[1,2-b:4,5-b´]dithiophene, the monomer of a polymer solar cells material, was synthesized from 4,8-dihydrobenzo[1,2-b:4,5b´]dithiophen-4,8-dione. The structure of the compound was determined by multinuclear NMR spectroscopy, including ¹H, ¹³C, ¹¹⁹Sn, ¹¹⁷Sn NMR, DEPT, selective 1D TOCSY and 2D NMR techniques including ¹H-¹H COSY, gHSQC and gHMBC. The ¹H, ¹³C, ¹¹⁹Sn, ¹¹⁷Sn NMR chemical shifts were assigned and the spectral features of the compound were discussed.

Key words: NMR, assignment, ¹¹⁹Sn NMR, 2,6-bis(trimethyltin)-4,8-bis(2-ethylhexyloxy)benzo[1,2-b:4,5-b´]dithiophene, , polymer

中图分类号:

O482. 53

王民昌*，张皋，徐敏，刘红利，栾洁玉，陈智群，齐珠钗. 2,6-双(三甲基锡)-4,8-双(2-乙基己氧基)苯并[1,2-b∶4,5-b´]二噻吩的合成与多核NMR研究[J]. 波谱学杂志.

WANG Min-chang*，ZHANG Gao，XU Min，LIU Hong-li，LUAN Jie-yu，CHEN Zhi-qun，QI Zhu-chai. Synthesis and Multinuclear NMR Study on 2,6-Bis(trimethyltin)-4,8-bis(2-ethylhexyloxy)benzo[1,2-b:4,5-b´]dithiophene[J]. Chinese Journal of Magnetic Resonance.

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