波谱学杂志 ›› 1989, Vol. 6 ›› Issue (2): 147-154.

• 研究论文 • 上一篇    下一篇

含分散第二相混合导体Li1+xV3O8(x=0.1)的磁共振研究

崔万秋, 陈文   

  1. 武汉工业大学
  • 收稿日期:1988-02-26 修回日期:1988-05-09 出版日期:1989-06-05 发布日期:2018-01-22

MAGNETIC RESONANCE STUDY OF MIXED CONDUCTOR Li1+xV3O8 (x=0. 1) CONTAINING DSPP

Cui Wanqiu, Chen Wen   

  1. Wuhan University of Technology
  • Received:1988-02-26 Revised:1988-05-09 Online:1989-06-05 Published:2018-01-22

摘要: 本文研究了含分散第二相混合导体Li1+xV3O8(x=0.1)体系的电性能和磁共振现象.经AC测定:表明室温下含6mol% α-Al2O3样品的总电导率是不含第二相样品的4-6倍.
由ESR和NMR定性、定量分析确定分散第二相微粒的加入,增加了样品的电子浓度,加快了样品中电子和离子的跃迁频率,降低了样品中Li+离子迁移激活能,总电导率增加.室温下,总电导率的增量主要取决于Li+离子电导率的贡献,电子电导率也有一定影响.

关键词: 分散第二相, 混合导体, 总电导率, 磁共振

Abstract: The electric property and magnetic resonance of mixed conductors Li1+xV3O8 (x=0.1) containing DSPP were studied. By AC measurement, the maximum of total conductivity for sample containing about 6 mol% α-Al2O3 was four or six times to that of pure Li1+xV3O8 (x=0.1) at room temperature.
That the addition of DSPP increases the electron density of the sample and electronic and ionic transport frequencies, decreases Li+ ionic transport activation energies i e., increases total conductivity of the sample was proved by ESR and NMR qualitative and quantitative analysis of the samples.
The increment of the total conductivity mainly depends on the contribution of the Li+ ionic conductivity, the electronic conductivity has a definite influence on it, too.

Key words: DSPP, Mixed Conductor, Total Conductivity, Magnetic Resonance