C-2,3,4,6,7-位含氧取代的9,10-二氢菲类化合物的NMR谱研究

波谱学杂志 ›› 1996, Vol. 13 ›› Issue (6): 589-594.

C-2,3,4,6,7-位含氧取代的9,10-二氢菲类化合物的NMR谱研究

李文魁¹, 张丹¹, 沈一行¹, 权丽辉¹, 杨峻山¹, 肖培根¹, 潘景歧², 吕木坚², 赵玉英³, 张如意³

1. 中国医学科学院、中国协和医科大学药用植物研究所, 北京 100094;
2. 北京大学化学与分子工程学院, 北京 100871;
3. 北京医科大学药学院, 北京 100083

收稿日期:1996-06-10 修回日期:1996-07-29 出版日期:1996-12-05 发布日期:2018-01-17
基金资助:
高校博士点专项基金资助项目

THE STUDIES ON THE NMR SPECTRA OF 9,10-DIHYDROPHENANTHRENE WITH OXY-SUBSTITUENTS AT C-2,3,4,6,7 POSITION

Li Wenkui¹, Zhang Dan¹, Shen Yixing¹, Ouan Lihui¹, Yang Junshan¹, Xiao Peigen¹, Pan Jingqi², Lü Mujian², Zhao Yuyin³, Zhang Ruyi³

1. Institute of Medicinal Plant Development, Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing 100094;
2. School of Chemistry and Molecular Engineering, Peking University, Beijing 100871;
3. School of Pharmaceutical Sciences, Beijing Medical University, Beijing 100083

Received:1996-06-10 Revised:1996-07-29 Online:1996-12-05 Published:2018-01-17

摘要/Abstract

摘要： 用2D NMR技术研究了获自朝鲜淫羊藿中的2-羟基-3,4,6,7-四甲氧基-9,10-二氢菲的结构,对其碳氢信号进行了全归属,并对文献报道的同类化合物的碳信号归属进行了评述.

关键词: C-2,3,4,6,7值含氧取代的9,10-二氢菲, 碳信号归属

Abstract: This paper deals with the studies of full assignments of ¹H and ¹³C NMR chemical shifts of 2-hydroxy-3,4,6,7-tetramethoxy-9,10-dihydrophenanthrene isolated from Epimedium koreanum by means of 2D NMR spectroscopic analyses.The assignments of ¹³C NMR chemcial shifts of similar compounds published in literatures were reappraised.

Key words: dihydrophenanthrene with oxy-substituents at C-2,3,4,6,7 position, NMR assignemts of ¹³C NMR chemical shifts

李文魁, 张丹, 沈一行, 权丽辉, 杨峻山, 肖培根, 潘景歧, 吕木坚, 赵玉英, 张如意. C-2,3,4,6,7-位含氧取代的9,10-二氢菲类化合物的NMR谱研究[J]. 波谱学杂志, 1996, 13(6): 589-594.

Li Wenkui, Zhang Dan, Shen Yixing, Ouan Lihui, Yang Junshan, Xiao Peigen, Pan Jingqi, Lü Mujian, Zhao Yuyin, Zhang Ruyi. THE STUDIES ON THE NMR SPECTRA OF 9,10-DIHYDROPHENANTHRENE WITH OXY-SUBSTITUENTS AT C-2,3,4,6,7 POSITION[J]. Chinese Journal of Magnetic Resonance, 1996, 13(6): 589-594.