波谱学杂志 ›› 1987, Vol. 4 ›› Issue (1): 67-72.

• 研究论文 • 上一篇    下一篇

Li2O-B2O3-P2O5系统非晶态混合骨架效应的NMR研究

崔万秋1, 邱建荣2   

  1. 1. 武汉工业大学;
    2. 上海建材学院
  • 收稿日期:1986-07-02 修回日期:1986-09-08 出版日期:1987-03-05 发布日期:2018-01-22

NMR STUDIES OF “MIXED FRAMEWORK EFFECT” OF NON-CRYSTALLINE Li2O-B2O3-P2O5 SYSTEM

Cui Wanqin1, Qiu Jianrong2   

  1. 1. Wuhan University of Technology;
    2. Shanghai Institute of Building Materials
  • Received:1986-07-02 Revised:1986-09-08 Online:1987-03-05 Published:2018-01-22

摘要: 用核磁共振对非晶态中B3+离子的微观结构进行了测定,结合Raman光谱的研究,对Li2O-B2O3-P2O5系统非晶态的性能(电导率、密度等)在P2O5/B2O3比约等于1时产生极值的原因从理论上作了阐明。

关键词: 混合骨架, 非晶态, 核磁共振波谱

Abstract: The environment of B3+ in the non-crystalline Li2O-B2O3-P2O5 system was examined by 11B NMR. The existance of extreme values in conductivity and density etc, at P2O5/B2O3 ratio of 1, was explained theoretically with the additional help of Raman spectrum.

Key words: mixed framework, non-crystalline, NMR