波谱学杂志 ›› 1998, Vol. 15 ›› Issue (5): 457-460.

• 研究论文 • 上一篇    下一篇

含穴醚N8O6的金属大环化合物的NMR研究

吴达旭, 于澍燕   

  1. 中国科学院福建物质结构研究所结构化学国家重点实验室, 福州 350002
  • 收稿日期:1998-03-10 修回日期:1998-05-12 出版日期:1998-10-05 发布日期:2018-01-17
  • 作者简介:吴达旭,男,55岁,副研究员

NMR STUDIES OF METALMACROCYCLIC COMPLEXES CONTAINING CRYPTAND N8O6

Wu Daxu, Yu Shuyan   

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou 350002
  • Received:1998-03-10 Revised:1998-05-12 Online:1998-10-05 Published:2018-01-17

摘要: 含有穴醚N8O6配体(L)的异金属和同金属大环化合物[Ag2NaL](ClO4)3(1),[Cu2L](BF4)(ClO4)*DMF*0.5EtOH(2),在溶液中,室温下,作了1H,13C和1H-13CHMQC NMR谱的测定,归属了所有的1H,13C的谱线.对其在溶液中的配位行为通过1H NMR试验作了简单的讨论.

关键词: 穴醚N8O6, 银-钠化合物, 铜化合物, 核磁共振波谱

Abstract: 1H, 13C and HMQC NMR spectra of hetero-metal Ag-Na and homo-metal Cu cryptates with cryptand N8O6, [Ag2NaL] (ClO4)3(1) and [Cu2L](BF4)(ClO4)*DMF*0.5EtOH(2) have been determined at room temperature in solution.All resonances of the proton and carbon of the complexes were assig ned.The solution coo rdination behavior of the complexes were studied by 1H NMR spectra.

Key words: Cryptand N8O6, Ag-Na complex, Cu complex, NMR