波谱学杂志 ›› 2010, Vol. 27 ›› Issue (1): 39-50.

• 恭祝徐广智先生八十华诞(专辑) • 上一篇    下一篇

中国自由基捕获技术发展30年

  

  1. 中国科学院 化学研究所,分子动态与稳态结构国家重点实验室,北京  100190
  • 收稿日期:2010-02-01 出版日期:2010-03-05 发布日期:2010-03-05
  • 基金资助:

    国家自然科学基金资助项目(90813021, 20875093).

Spin Trapping in China: An Overview of the Past 30 Years

  1. State Key Laboratory for Structural Chemistry of  Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Received:2010-02-01 Online:2010-03-05 Published:2010-03-05
  • Supported by:

    国家自然科学基金资助项目(90813021, 20875093).

摘要:

本文简要回顾了30年来国内在自由基捕获技术(spin trapping)领域的研究进展,其中包括新型自由基捕获探针的分子设计与合成,探针结合EPR波谱方法在光、电化学反应以及生物领域的应用实例. 最后,结合国内外自由基捕获技术现状讨论了它的未来发展前景.

关键词: 电子顺磁共振(EPR), 自由基捕获技术, 自由基

Abstract:

In this review, we briefly summarized the historical development of spin trapping-EPR technology during the past 30 years in China, including the molecular design and synthesis of new spin traps and the applications of spintrapping experiments coupled with EPR detection in photochemistry, electrochemistry and biology. Based on the present status of spin trapping research, finally we discussed the prospects for the future development of spin trapping technique.

Key words: EPR, spin trapping, free radicals

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