波谱学杂志 ›› 2008, Vol. 25 ›› Issue (3): 408-414.

• 研究简报 • 上一篇    下一篇

含多氟烷基三环螺环化合物的合成及波谱学结构研究

施志坚1,2*; 赵杨1; 曹卫国1,2; 张顺利1; 刘梅1; 邓红梅3   

  1. (1. 上海大学 化学系,上海 200444;2. 中国科学院 上海有机化学研究所有机氟化学重点实验室,上海 200032; 3. 上海大学 测试中心,上海 200444)
  • 收稿日期:2007-09-07 修回日期:2007-12-12 出版日期:2008-09-05 发布日期:2009-12-05
  • 通讯作者: 施志坚

Synthesis and Structure Elucidation of New Spiro Compounds with Polyfluoroalkyl Group

SHI Zhi-jian1,2*; ZHAO Yang1; CAO Wei-guo1,2; ZHANG Shun-li1; LIU Mei1, DENG Hong-mei3   

  1. (1.Department of Chemistry, Shanghai University, Shanghai 200444, China; 2.Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China; 3.The Center for Tesing, Shanghai University, Shanghai 200444, China)
  • Received:2007-09-07 Revised:2007-12-12 Online:2008-09-05 Published:2009-12-05
  • Contact: SHI Zhi-jian

摘要: 选择合适的反应条件,设计合成了含长链多氟烷基的螺环化合物. 通过对反应产物的1H MR、 13C NMR、2D NMR和IR、MS谱及X-衍射图的分析,对最终反应产物10-(5-氯-2,2,3,3,4,4,5,5-八氟-戊烷基)-11-(1-碘-甲基)-6,14-二氧杂-螺[4.2.4.2]十四烷-7,13-二酮进行了结构确证和分析. 讨论了该类化合物的谱学行为和空间构型.

关键词: 多氟烷基, 螺环化合物, 波谱分析, X-衍射

Abstract: A spiro compound with polyfluoroalkyl group was synthesized. Its structure was elucidated by 1H NMR, 13C NMR, IR, MS, 2D NMR and X-diffraction. The spectral features and the space structure of the compound were also discussed.

Key words: polyfluoroalkylated, spiro compound, structure, X-diffraction

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