波谱学杂志 ›› 2006, Vol. 23 ›› Issue (4): 545-546.

• 博士论文摘要 • 上一篇    下一篇

局限空间中水的相变与动态学研究

作者:黄圣言 导师:黄良平   

  1. (台湾大学 化学研究所, 台湾 台北)
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:2006-12-05 发布日期:2009-12-05
  • 通讯作者: 黄圣言

Liquid-Liquid Phase Transitions of Water in Confinement by T1 and DQF NMR Studies

Author: HWANG Dennis W Advisor: HWANG Lian-pin
  

  1. (Dept. of Chemistry, NTU, Taipei, Taiwan)
  • Received:1900-01-01 Revised:1900-01-01 Online:2006-12-05 Published:2009-12-05
  • Contact: HWANG Dennis W

摘要: 在本篇论文中,主要讨论水分子在局限空间中的运动及相变行为,所使用的方法为双量子过滤核磁共振光谱及T1反转回覆光谱,体系为利用MCM-41吸附不同量的重水. 本研究中所使用的这两种光谱方法各有其独特之处,其中双量子过滤核磁共振光谱是利用被吸附的重水分子中氘核残余四极作用力所产生双量子讯号进行侦测,因此是特别针对表面吸附的水分子进行观测, 而T1反转回覆光谱则是侦测整体孔洞內水分子的行为,借由两种光谱的谱线分析相互比对,得到在MCM-41內各层水分子对温度变化的完整动态学行为. 在描述表面水分子运动上,采用的是修改过的锥体模型,主要将水分子分成相对其对称轴的摇摆运动及旋转运动,在研究中发现,表面水分子是被MCM-41表面单独的SiOH所吸附,比例上为一个水分子对一个SiOH,而表面分子的运动会受到第二层水分子的形成与否所影响,一但第二层水分子 的量够多时,其平移扩散运动会借由碰撞影响表面水分子的摇摆运动,而且在孔洞中属于非表面吸附的水分子,在随温度变化至240~250 K之间时会有相变发生,相变的温度则会随水量充填在MCM-41內的多寡而改变,当水分子越多时,因为彼此间空间有限,使得氢键网路结构与一般正常在大量水分子体系的结构有些相异,因此使得相变温度会随之下降. 除此之外,本研究中亦提出不同的双量子过滤核磁共振脉冲序列以及不同的模型来讨论.

关键词: 核磁共振光谱, 双量子, 过冷水, MCM-41

Abstract: Dynamics of water adsorbed on MCM-41 has been investigated by 2H double quantum filtered (DQF) NMR and T1 inversion-recovery NMR. The modified cone model is employed in this study. From temperature dependent studies with various water loadings on MCM-41, it is found that there are different sites for water adsorption on MCM-41. The signal of water molecules in the slow site dominates in the observed DQF NMR. The influence of silanol groups on the MCM-41 surface strongly affects the motion of water molecules in the slow site, resulting in a residual quadrupolar interaction. As the signal of water in fast site dominates that observed in single quantum spectra, it also appears in DQF spectra through an exchange process. It is found that the single SiOH group is the major adsorption site on MCM-41 surface and the ratio is one water molecule to on SIOH group. The wobbling motion of the water in slow site is also influenced by the translation diffusion of the second monolayer water through collision. The phase transitions of water in fast motion site are also found. The results indicate that the phase transition temperature varies with different hydration. Higher hydration sample may cause the more serious structure distortion in the pore. Therefore, the lower phase transition temperature is found in the higher hydration sample. Moreover, with the low hydration MCM-41 sample, it shows that there is only single layer of water molecules on the surface. Alternative pulse sequence for DQF NMR, which is called spinlock double quantum filtered (SLDQF) NMR, and reorientation mediated by 2D jump diffusion model have also been developed in this study.

Key words: NMR, double quantum, surpercoal water, MCM-41