波谱学杂志 ›› 1996, Vol. 13 ›› Issue (4): 377-381.

• 研究论文 • 上一篇    下一篇

化合物(Et4N)2[Pd2(mp)2(μ-mpH)2]的NMR研究

吴达旭, 施继成, 康北笙   

  1. 中国科学院福建物质结构研究所结构化学国家重点实验室, 福州 350002
  • 收稿日期:1995-11-06 修回日期:1995-12-25 出版日期:1996-08-05 发布日期:2018-01-17

NMR STUDIES ON THE COMPOUND(Et4N)2[Pd2(mp)2(μ-mph)2]

Wu Daxu, Shi Jicheng, Kang Beisheng   

  1. Stat Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002
  • Received:1995-11-06 Revised:1995-12-25 Online:1996-08-05 Published:2018-01-17

摘要: 采用1H-1H COSY,HMQC、HMBC等2D NMR技术对化合物(Et4N)2[Pd2(mp)2(μ-mpH)2]进行1H、13C NMR谱数据分析与归属,表明它在DMSO溶液中仍保持原有固体状态的分子结构.

关键词: 化合物[Et4N)[Pd2(mp)2(μ-mpH)2], 邻巯基苯酚, 同核质子相关谱, 异核多量子相干相关谱, 异核多键相关谱

Abstract: In this paper simulated proton spectrum and Homo-COSY,Hetero-CHCOR 2D NMR techniques were used to analyze and assign the 1H and 13C NMR spectra of the Compound (E4N)2[Pd2(mp)2(μ-mph)2].The results indicate that the Compound isstable in DMSO solution as their molecular structures remain the same as those in the solid state.

Key words: Compound (Et4N)2[Pd2(mp)2(μ-mph)]2, o-mercaptophenol, 1H-1H COSY, HMQC, HMBC