波谱学杂志 ›› 1989, Vol. 6 ›› Issue (3): 277-281.

• 研究论文 •    下一篇

Cu2+-柞蚕丝蛋白络合物的ESR研究

纪涛1, 宋永哲1, 刘振勤2, 刘姝2, 王云翘3, 贺文琴3, 王继红3   

  1. 1. 中国科学院大连化学物理研究所;
    2. 辽宁大学;
    3. 大连经工业学院
  • 收稿日期:1988-04-16 修回日期:1988-10-25 出版日期:1989-09-05 发布日期:2018-01-22
  • 基金资助:
    国家自然科学基金项目

ESR STUDY OF Cu2+-TUSSAH SILK PROTEIN COMPLEXES

Ji Tao1, Song Yongzhe1, Liu Zhenqin2, Liu Shu2, Wang Yunqiao3, He Wenqin3, WangJihong3   

  1. 1. Dalian Institute of Chemical Physics, Academia Sinica;
    2. Liaoming University;
    3. Dalian College of Light Industry
  • Received:1988-04-16 Revised:1988-10-25 Online:1989-09-05 Published:2018-01-22

摘要: 本文用ESR、UV和IR研究了Cu2+-柞蚕丝蛋白络合物,确定了铜的价态及其配位体,给出了化学结构模型,用实验参数计算了配位键参量和配位场能.

关键词: 柞蚕丝, ESR

Abstract: The Cu2+-tussah silk protein complexes have been studied by ESR, UV and IR. On the basis of these spectra and ligand field theory calculation, the ligands at the Cu2+, the oxidation state of Cu2+ and the structure model of these complexes were proposed. MoreBack

Key words: Tussah silk, ESR