波谱学杂志 ›› 1986, Vol. 3 ›› Issue (2): 99-104.

• 研究论文 •    下一篇

三稠环系三唑磷茂啉的化学IV.系列化合物Ⅱ和Ⅲ的31P和13C NMR研究

曹志松1, 张景龄1, 许奎钫2   

  1. 1 华中师范学院农药化学研究所;
    2 中国科学院武汉物理研究所
  • 收稿日期:1985-01-30 修回日期:1985-06-08 出版日期:1986-06-05 发布日期:2018-01-23
  • 基金资助:
    中国科学院基金资助

THE CHEMISTRY OF FUSED TRICYCLIC TRIAZO-PHOSPHOLENE Ⅳ.THE 31P AND 13C NMR STUDIES OF COMPOUNDS Ⅱ AND Ⅲ

Zhang Jinglin1, Cao Zhisong1, Xu Kuifang2   

  1. 1 Research Institute of Pesticide chemistry, Huazhong Normal University, Wuhan;
    2 Wuhan Institute of Physicis, Academia Sinica
  • Received:1985-01-30 Revised:1985-06-08 Online:1986-06-05 Published:2018-01-23

摘要: 本文通过对两个新的三稠环系三唑磷茂啉系列化合物Ⅰ和Ⅱ的13C NMR谱的解析,初步指定了谱线的归属。同时,发现了系列化合物Ⅱ中31P NMR化学移值与Ar基上取代基的Hammett σ常数呈线性关系。

Abstract: In this paper, the 13C NMR lines of two new series of fused tricyclic triazophospholene compounds, 1-phenyl-5-aroxyl derivatives Ⅱ and 1-phenyl -5-alkoxyl derivatives Ⅲ, were assigned to each carbon, and the correlation between δ31P values and σ constants of substituents on Ar groups was reported.