部分季胺盐化聚4-乙烯基吡啶-Cu(Ⅱ)络合物的电子自旋共振波谱研究

波谱学杂志 ›› 1984, Vol. 1 ›› Issue (5): 451-458.

部分季胺盐化聚4-乙烯基吡啶-Cu(Ⅱ)络合物的电子自旋共振波谱研究

林宜超¹, 邹斌²

1. 福建省测试技术研究所;
2. 西南交通大学

收稿日期:1984-05-22 修回日期:1984-07-27 出版日期:1984-09-05 发布日期:2018-01-25

STUDY ON ELECTRON SPIN RESONANCE SPECTRA OF THE COPPER (Ⅱ) COMPLEX OF PARTIALLY QUATERNIZED POLY (4-VINYLPYRIDINE)

Lin Yichao¹, Zon Bing²

1. Fujian Institude of Measurement and Testing Technologe;
2. Southwest Jiao-Tong University

Received:1984-05-22 Revised:1984-07-27 Online:1984-09-05 Published:2018-01-25

摘要/Abstract

摘要： 本文测定了用溴乙烷部分季胺盐化聚4-乙烯基吡啶(EBQP₄VP)-CU(Ⅱ)络合物的可见光谱和电子自旋共振(ESR)波谱,研究了温度、配位体/Cu(Ⅱ)摩尔比、溶液的pH值和高分子配位体的季胺盐化度(Q)的变化对高分子-Cu(Ⅱ)络合物配位结构的影响。在配位体/Cu(Ⅱ)摩尔比20:1下,随着溶液pH值增大,或是Q值减小,溶液的比浓粘度下降,因而高分子链形态趋于卷曲,催化氢醌的氧化活性增大,此时高分子-CU(Ⅱ)络合物[CuL₄](L为高分子配位体)的配位结构呈四方畸变的八面体结构。

Abstract: Visible and electron spin resonance spectra of the copper (I) comple of partially quaternized poly(4-vinylpyridine) by ethyl bromide(EBQP₄VP) by ethyl bromide(EBQP₄VP) were measured. Effects of varying temperature, Iigand/Cu(J) mole ratio, pH value of solution and the percentage of quater-nization(Q) of polymer ligand on the coordination structure of polymer-Cu (I) complex were investigated. At ligand/Cu (Ⅱ) mole ratio 2011, the reduced viscosities of solution decrease with increasing pH value of solution or decreasing Q value. Hence the shape of the polymer chain is markedly crimple, the oxidation activity of catalytic hydroquinone increases. In this time the coordination of polymer-Cu(Ⅱ) complex[CuL₄] (L is polymer ligand) is a tetragonally distorted octahedral structure.

林宜超, 邹斌. 部分季胺盐化聚4-乙烯基吡啶-Cu(Ⅱ)络合物的电子自旋共振波谱研究[J]. 波谱学杂志, 1984, 1(5): 451-458.

Lin Yichao, Zon Bing. STUDY ON ELECTRON SPIN RESONANCE SPECTRA OF THE COPPER (Ⅱ) COMPLEX OF PARTIALLY QUATERNIZED POLY (4-VINYLPYRIDINE)[J]. Chinese Journal of Magnetic Resonance, 1984, 1(5): 451-458.