Steroidal Saponins Compounds in Tupistra: Structures and 13C NMR Features

Abstract

Abstract:

By summarizing published literatures, the structural and ¹³C NMR spectral features of steroidal saponins isolated from Tupistra were analyzed. So far, 53 identified steroidal saponins compounds had been isolated from the plant, including 27 spirostanols and their glycosides, 24 furostanols and their glycosides, and 2 furospirostanols. The ¹³C NMR spectra of different steroidal saponins show different features that are related to skeletons and type and position of the substituent groups in the compounds. The findings are helpful for structure elucidation and assignments of the spectroscopic signals of such compounds.

Key words: Tupistra, steroidal saponins, ¹³C NMR, spectral features, structure, meta-analysis

CLC Number:

O482.53

LIU Cheng-Xiong, XUE Yan-Hong, GUO Zhi-Yong, ZU Kun, LI Xiao-Cong. Steroidal Saponins Compounds in Tupistra: Structures and ¹³C NMR Features[J]. Chinese Journal of Magnetic Resonance, 2011, 28(1): 115-126.

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Steroidal Saponins Compounds in Tupistra: Structures and ¹³C NMR Features

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