Chinese Journal of Magnetic Resonance ›› 2004, Vol. 21 ›› Issue (2): 243-247.

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MAGNETIC PROPERTIES OF THE COPPER COMPLEX OF DITHIOLATE [STHZ]AND PHENANTHROLINE-5,6-DIONE

 PAN Qiang-Cai1,  PENG-Zheng-He2   

  1. 1.Zhumadian  College, Zhumadian 463000, China;
    2.College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, China
  • Received:2003-10-14 Revised:2003-11-20 Online:2004-06-05 Published:2004-06-05
  • Supported by:

    国家自然科学基金资助项目(29471022,29771025),河南省教育厅重点科研资助项目(2000150047).

Abstract:

The microcrystalline structure and magnetic properties of the complex CuLL′(L=mnt2-},1,2-dicyano-1,2-dithiolate; L′=phen-5,6-odione,1,10-phenanthroline-5,6-dione)were studied by variable-temperature susceptibility measurements and EPR. The results showed that the complex exist in the forms of microcrystalli ne particle and high-spin tetracoordinate complex, and possesses remarkable para
magnetism. The experimental EPR observations for the complex are explained by theory.

Key words: dithiolate, phenanthroline-5,6-dione, magnetism, EPR, copper

CLC Number: