波谱学杂志

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美登木属植物中木栓烷型三萜的结构及其13C NMR 波谱特征

普德兵,高嫄,李蓉涛,李海舟*   

  1. 昆明理工大学 生命科学与技术学院,植物化学实验室,云南 昆明 650500
  • 收稿日期:2013-09-26 修回日期:2014-07-18 出版日期:2014-09-05 发布日期:2014-09-05
  • 作者简介:普德兵(1989-),男,云南玉溪人,硕士研究生,主要从事天然药物开发研究. *通讯联系人:李海舟,电话:0871-65192340,E-mail:lihaizhou@hotmail.com.
  • 基金资助:

    国家自然科学基金资助项目(81360643,31060054).

Structures and 13C NMR Features of Friedelane Triterpenoid Compounds in Maytenus: A Review

PU De-bing,GAO Yuan,LI Rong-tao,LI Hai-zhou*   

  1. Phytochemistry Laboratory, Faculty of Life Science and Technology, Kunming University of Science and Technology, Kunming 650500, China)
  • Received:2013-09-26 Revised:2014-07-18 Online:2014-09-05 Published:2014-09-05
  • About author:*Corresponding author:LI Hai-zhou, Tel: 0871-65192340, E-mail: lihaizhou@hotmail.com.
  • Supported by:

    国家自然科学基金资助项目(81360643,31060054).

摘要:

卫矛科美登木属(Maytenus)植物因发现具有较强抗肿瘤活性而备受关注,其中木栓烷型三萜是主要活性成分之一,并具有较特征的A 环或A/B 环均为芳香化结构.该文综述了近年(1995~2013 年)来美登木属植物中木栓烷型三萜的结构类型及其13C NMR 特征,为这类化合物的结构鉴定和波谱数据归属提供参考.

关键词: 13C NMR, 美登木属, 三萜类化合物, 木栓烷型, 结构类型

Abstract:

Maytenus species are shown to have antitumor activity. Friedelane triterpenoid is found to be one of most active components, especially aromatic friedelane triterpenoid with A ring or A/B rings. In this study, the chemical structures and of and 13C NMR characteristics of friedelane triterpenoids from Maytenus reported in the literature from 1995 to 2013 are summarized and reviewed. The findings are potentially useful for structure elucidation and assignment of the spectroscopic signals of this type of compounds.

Key words: 13C NMR, maytenus, triterpenoids, friedelane, structure

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