漆酚二聚体模型化合物的NMR研究

波谱学杂志 ›› 1989, Vol. 6 ›› Issue (3): 358-362.

漆酚二聚体模型化合物的NMR研究

邱峰, 裘鉴卿, 袁汉珍, 钱保功

中国科学院武汉物理所波谱与原子分子物理开放研究实验室

收稿日期:1988-03-12 修回日期:1988-04-13 出版日期:1989-09-05 发布日期:2018-01-22

NMR STUDIES ON THE MODEL COMPOUND OF URUSHIOL DIMER

Qiu Feng, Qiu Jianqing, Yuan Hanzhen, Qian Baogong

Laboratory of Magnetic Resonance and Atomic and Molecular Physics, Wuhan Institute of Physics, Academia Sinica, PR China

Received:1988-03-12 Revised:1988-04-13 Online:1989-09-05 Published:2018-01-22

摘要/Abstract

摘要： 为了确证漆酚二聚体的主要组分的聚合点是否形成烷基芳醚,本文合成了新的模型化合物CH₂CH₂C-O-OHCH₃,并进行了2D-NMR和质谱研究,完全确定了模型化合物的结构和谱线归属,从而确定了漆酚二聚体的主要组分聚合点有与此化合物相同的结构单元,为进一步直接研究并确定漆酚二聚体组分结构打下了基础.

关键词: 两维核磁共振, 漆酚二聚体

Abstract: In order to determine the structure of alkyl aromatic ether of urushiol dimer, the model compound CH₃ CH₂ C-O-OHCH₃ was synthesized.The structue and the assignment of resonances were confirmed by 2D-NMR and MS. The results have shown that there is the same structural unit, 2-butyl phenyl ether, in the urushiol dimer.

Key words: 2D-NMR, Urushiol dimer

邱峰, 裘鉴卿, 袁汉珍, 钱保功. 漆酚二聚体模型化合物的NMR研究[J]. 波谱学杂志, 1989, 6(3): 358-362.

Qiu Feng, Qiu Jianqing, Yuan Hanzhen, Qian Baogong. NMR STUDIES ON THE MODEL COMPOUND OF URUSHIOL DIMER[J]. Chinese Journal of Magnetic Resonance, 1989, 6(3): 358-362.