二茂铁基化合物的ESR研究进展

doi:10.11938/cjmr20160314

摘要/Abstract

摘要：

二茂铁基化合物因具有独特的氧化还原、电、光、磁和催化性能，而被广泛研究与应用．电子自旋共振（ESR）技术是观察物质顺磁性最直接的手段，在研究二茂铁基化合物的电子结构、电子转移和分子间相互作用等方面具有独特的优势．ESR技术还具有灵敏度高、样品处理简单、直接检测不破坏样品等优点．该文综述了二茂铁基化合物的ESR研究进展．

关键词: 电子自旋共振(ESR), 电子结构, 综述, 二茂铁基化合物

Abstract:

Ferrocenyl compounds were widely used and extensively studied due to their excellent thermal, redox, electronic, optic, magnetic and catalytic properties. Electron spin resonance (ESR) is a method that can be used to study paramagnetic behaviors, electronic structure, electron transfer and molecular interactions of ferrocenyl compounds. In addition, ESR possesses advantages such as high sensitivity, easy sample treatment and nondestructive testing. This article reviewed recent progresses in ESR studies on ferrocenyl compounds.

Key words: ESR, electronic structure, review, ferrocenyl compounds

中图分类号:

O482.53

杨贤鹏, 俞豪杰, 王立. 二茂铁基化合物的ESR研究进展[J]. 波谱学杂志, 2016, 33(3): 491-501.

YANG Xian-peng, YU Hao-jie, WANG Li. Recent Progresses in ESR Studies on Ferrocenyl Compounds[J]. Chinese Journal of Magnetic Resonance, 2016, 33(3): 491-501.

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