波谱学杂志 ›› 1997, Vol. 14 ›› Issue (5): 375-378.

• 研究论文 • 上一篇    下一篇

一些羰基钼化合物的95Mo NMR研究

吴达旭, 陈忠, 卢葛覃, 潘国华, 孙好芬, 庄伯涛   

  1. 中国科学院福建物质结构研究所, 结构化学国家重点实验室, 福州 350002
  • 收稿日期:1997-03-21 修回日期:1997-05-23 出版日期:1997-10-05 发布日期:2018-01-22
  • 作者简介:吴达旭,男,53岁副研究员

95Mo NMR STUDIES ON SOME CARBONYLMOLYBDENUM COMPOUNDS

Wu Daxu, Chen Zhong, Lu Getan, Pan Guohua, Sun Haofen, Zhuang Botao   

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Thzhou, 350002
  • Received:1997-03-21 Revised:1997-05-23 Online:1997-10-05 Published:2018-01-22

摘要: 测定了12个羰基钼化合物的95Mo NMR谱,比较了它们的化学位移,简单地讨论了Mo原子的氧化价态、相同金属之间、不同金属之间相互作用及配体取代基等因素对化学位移的影响.

关键词: 羰基钼化合物, 95Mo NMR

Abstract: The 95Mo NMR chemical shifts of 12 carbonylmolybdenum compounds have been determined. The influential factors on 95Mo chemical shifts such as the oxidation state of molybdenum atom,interactions between homometals, and between heterometals, and ligand substitution etc. have been discussed briefly.

Key words: Carbonylmolybdenum compounds, 95Mo NMR