波谱学杂志 ›› 1994, Vol. 11 ›› Issue (4): 419-425.

• 研究论文 • 上一篇    下一篇

氮-14远程核四极共振谱仪

李鲠颖1, 蒋瑜1, 吴先球2, 邬学文1   

  1. 1. 华东师范大学分析测试中心, 上海 200062;
    2. 华南师范大学物理系, 广州 510213
  • 收稿日期:1993-08-16 出版日期:1994-12-05 发布日期:2018-01-20
  • 基金资助:
    本项目由上海市科委“青年科技启明星计划”资助

NITROGEN-14 REMOTE NUCLEAR QUADRUPOLE RESONANCE SPECTROMETER

Li Geneying1, Jiang Yu1, Wu Xianqiu2, Wu Xuewen1   

  1. 1. Analytical Center, East China Normal University, Shanghai 200062;
    2. Department of Physics, South China Normal University, Guangzhou 510213
  • Received:1993-08-16 Online:1994-12-05 Published:2018-01-20

摘要: 为了满足检测与探头有一定距离的含氮化合物的核四极共振信号,本文研制了一台结构简单,造价低廉的核四极共振操测仪.它利用了脉冲付里叶变换技术,可将获得的核自由感应衰减信号或者回波信号进行相干累加.整个系统分硬件和软件两大部分.前者由射频脉冲放大器(约500W脉冲输出功率),探头,接收机,MCS-96型单片机和PC机构成.后者由单片机上的脉冲序列程序与PC机上的数值信号处理程序组成.利用这台谱仪,可以在几十秒时间内得到距离探头线圈10cm内的典型14 N样品的核四极共振谱.

关键词: 含氮化合物, 核四极共振, 远程探测

Abstract: To meet the requirement of NQR measurement of 14N compounds outside the probe-head, an NQR speetrometer with simplicity and economy was built. It utilizes the pulsed Fourier transform technique to apouire FID or echo signais for coherent accumulations. The whole system consists of two parts. The first part, hardware component, is made up of a radio-frcquency pulse gcnerator with power output of about 500 W, a probe-head, a receiver, an MCS-96 series single-chip micro-processor (8097BH) and an IBM pcrsonal computcr (PC/386). The second part includes softwam running in the single-chip micro-proessor and programs for the PC to handle numerical time-domain NQR data. With this apbectrometer, NQR signals from typical 14N samples of tens of grarns and within 10cm distance from the probe can be deteded in tens of seconds.

Key words: 14N compounds, Nuclear quadrupole rasenance, Remote detoction