强偶合系统的弱偶合方法处理

波谱学杂志 ›› 1988, Vol. 5 ›› Issue (4): 357-366.

强偶合系统的弱偶合方法处理

高汉宾

武汉物理所波谱与原子分子物理开放研究实验室

收稿日期:1987-10-24 修回日期:1988-01-18 出版日期:1988-12-05 发布日期:2018-01-22

STRONG COUPLING SYSTEMS TREATED BY WEAK COUPLING SYSTEM METHOD

Gao Hanbin

Laboratary of Magnetic Resonance and Atomic and Molecular physics, Wuhan Institute of physics, Academia Sinica, Wuhan, China

Received:1987-10-24 Revised:1988-01-18 Online:1988-12-05 Published:2018-01-22

摘要/Abstract

摘要： 本文提出了强偶合系统的弱偶合方法处理。利用么正变换,把强偶合系统的哈密顿变成弱偶合系统哈密顿的形式,射频脉冲也作相同的变换,这样强偶合系统的多脉冲实验就能在弱偶合空间{φ}中计算。以AB体系的COSY和2D-J谱为例作了计算和讨论。

关键词: 么正变换, 积函数, 积算符

Abstract: A method for describing strong coupling systems by weak coupling system method is suggested. Hamiltonian of strong coupling system was transfered into the form of weak coupling system by using unitary transformation, the same transformation was also applied to rf pulses. The multiple pulse experiments for strong coupling system were calculated in weak coupling space {φ}. As an example, COSY and 2D-J spectra in AB system were calculated.

Key words: Unitary transformation, Product functions, Product operators

高汉宾. 强偶合系统的弱偶合方法处理[J]. 波谱学杂志, 1988, 5(4): 357-366.

Gao Hanbin. STRONG COUPLING SYSTEMS TREATED BY WEAK COUPLING SYSTEM METHOD[J]. Chinese Journal of Magnetic Resonance, 1988, 5(4): 357-366.

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