某些酸性磷膦酸酯VO(Ⅱ)络合物在氯仿中ESR研究

波谱学杂志 ›› 1987, Vol. 4 ›› Issue (2): 121-130.

某些酸性磷膦酸酯VO(Ⅱ)络合物在氯仿中ESR研究

陈德余¹, 徐元植¹, 王树源¹, 周澄明²

1. 浙江大学化学系杭州;
2. 中国科学院上海有机化学研究所

收稿日期:1986-09-18 出版日期:1987-06-05 发布日期:2018-01-22

ESR STUDY OF SOME OXOVANDIUM ACIDIC PHOSPHATES (PHOSPHONATES) COMPLEXES IN CHLOROFORM

Chen Deyu¹, Xu Yuanzhi¹, Wang Shuyuan¹, Zhou Chengming²

1. Department of Chemistry, Zhejing University, Handzhou;
2. Shanghai Institute of Organic Chemistry, Academia Sinica

Received:1986-09-18 Online:1987-06-05 Published:2018-01-22

摘要/Abstract

摘要： 本文对某些酸性磷(膦)酸酯VO(Ⅱ)络合物在氯仿中室温ESR谱做了进一步的解析,并测得这类络合物在氯仿中在液氮温度下ESR波谱参数,计算了它们的键参数,对这类络合物的成键特性进行了讨论。

关键词: 酸性磷(膦)酸醋, VO(Ⅱ)络合物, 氯仿, ESR波谱

Abstract: ESR spectra of some oxovanadium acidic phosphates (phosphonates) complexes in chloroform measured at room temperature were further analyzed. ESR spectral parameters of these complexes in chloroform at liquid nitrogen temperature were determined.Their bond parameters were calculated and the bonding character between vanadium (Ⅳ) and ligands is discussed in this paper.

Key words: acidic phosphates and phosphonates, oxovandium(Ⅱ)complexes, chloroform, ESR spectra

陈德余, 徐元植, 王树源, 周澄明. 某些酸性磷膦酸酯VO(Ⅱ)络合物在氯仿中ESR研究[J]. 波谱学杂志, 1987, 4(2): 121-130.

Chen Deyu, Xu Yuanzhi, Wang Shuyuan, Zhou Chengming. ESR STUDY OF SOME OXOVANDIUM ACIDIC PHOSPHATES (PHOSPHONATES) COMPLEXES IN CHLOROFORM[J]. Chinese Journal of Magnetic Resonance, 1987, 4(2): 121-130.

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