固体NMR研究MOFs吸附和分离过程中的主客体相互作用
Solid-state NMR Investigation of the Host-guest Interactions in Gas Adsorption and Chemical Separation Using MOFs as Adsorbents
固体NMR研究MOFs吸附和分离过程中的主客体相互作用 |
| 贺彩艳,肖宇情,李申慧,徐君,邓风 |
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Solid-state NMR Investigation of the Host-guest Interactions in Gas Adsorption and Chemical Separation Using MOFs as Adsorbents |
| HE Caiyan,XIAO Yuqing,LI Shenhui,XU Jun,DENG Feng |
| 图7 (a)吸附1 mol/L 1:1甘油:乙醇溶液的ZIF-11的单脉冲和交叉极化13C NMR谱；(b) 1:1的甘油:乙醇溶液吸附在ZIF-11随时间变化的单脉冲13C NMR谱；(c) ZIF-11至ZIF-7-lll的结构转变[ |
| Fig. 7 (a) 13C single pulse (SP) and cross polarization (CP) NMR spectra of ZIF-11 loaded with 1 mol/L 1:1 glycerol:ethanol solution; (b) Time-dependence of 13C SP NMR spectra of ZIF-11 loaded with 1:1 glycerol:ethanol solution; (c) Structural transformation of ZIF-7-III from ZIF-11 upon the removal of guest solvents[ |
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