固体NMR研究MOFs吸附和分离过程中的主客体相互作用
Solid-state NMR Investigation of the Host-guest Interactions in Gas Adsorption and Chemical Separation Using MOFs as Adsorbents
固体NMR研究MOFs吸附和分离过程中的主客体相互作用 |
| 贺彩艳,肖宇情,李申慧,徐君,邓风 |
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Solid-state NMR Investigation of the Host-guest Interactions in Gas Adsorption and Chemical Separation Using MOFs as Adsorbents |
| HE Caiyan,XIAO Yuqing,LI Shenhui,XU Jun,DENG Feng |
| 图1 (a, b) 110 K下乙炔吸附在Cu(INAIP)的单晶X-射线衍射结构；(c) DFT优化的乙炔局部结构；(d)羧酸基团的氧位和C2H2的电子密度图；(e)吸附C2D2的Cu(INAIP)的变温静态2H NMR谱[ |
| Fig. 1 (a, b) SCXRD structure of C2H2 loaded on Cu(INAIP) at 110 K; (c) DFT optimized C2H2 local environment; (d) Electron density plots of C2H2 and oxygen sites of the carboxylate groups; (e) Variable temperature (VT) 2H NMR spectra of C2D2 loaded on Cu(INAIP)[ |
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