二甲基胺阳离子掺杂甲胺铅溴钙钛矿材料的固体NMR研究
马开阳,乔文成,王雪璐,姚叶锋

A Solid-state NMR Study of Dimethylamine Cation-doped MAPbBr3 Perovskite Materials
MA Kaiyang,QIAO Wencheng,WANG Xuelu,YAO Yefeng
图6 甲基发生内旋转时,(a) DMA离子的运动模型和(b) DMA氘代甲基的模拟2H NMR谱.谱图模拟条件:C-D键与C-N轴之间的夹角θ = 70?,运动速率达到fast limit
Fig. 6 (a) The motion model of DMA cation and (b) the simulated 2H NMR spectrum of CD3 in DMA when methyl groups undergo the intrinsic rotation along C-N bond. Simulation condition: the angle between C-D bond and C-N axis θ = 70?, and the rotation rate reaches fast limit