二甲基胺阳离子掺杂甲胺铅溴钙钛矿材料的固体NMR研究 |
马开阳,乔文成,王雪璐,姚叶锋 |
A Solid-state NMR Study of Dimethylamine Cation-doped MAPbBr3 Perovskite Materials |
MA Kaiyang,QIAO Wencheng,WANG Xuelu,YAO Yefeng |
图10 (a) MA0.6DMA0.4(d6)PbBr3的固体静态2H NMR谱,实验温度为150~300 K;(b) DMA的模拟2H NMR谱.谱图模拟条件:DMA发生双重旋转运动,θ值取54.7?,绕旋转轴Rc的旋转速率(Ω)从100 kHz变化到fast limit |
Fig. 10 (a) Static solid state 2H NMR spectra of MA0.6DMA0.4(d6)PbBr3. The experimental temperatures range from 150 K to 300 K; (b) The simulated 2H NMR spectra of DMA. Spectral simulation conditions: DMA undergoes the double rotation. The angle between Rc and C-N axis is θ = 54.7?, and the rotation rates (Ω) range from 100 kHz to fast limit |