MAPbCl3钙钛矿中甲胺阳离子运动的固体2H NMR研究
Solid-state 2H NMR Study of the Motion of CH3NH3+ in MAPbCl3 Perovskite
MAPbCl3钙钛矿中甲胺阳离子运动的固体2H NMR研究 |
| 梁佳琪,乔文成,姚叶锋 |
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Solid-state 2H NMR Study of the Motion of CH3NH3+ in MAPbCl3 Perovskite |
| Jia-qi LIANG,Wen-cheng QIAO,Ye-feng YAO |
| 图3 MA的(a)运动模型Ⅱ和(b)拟合2H NMR谱.拟合过程中，围绕C-N键内旋转的速率和局部晃动的速率均在fast limit区间，σ值从0˚增加到20˚.为了使图更加清晰，MA中部分原子被省略 |
| Fig.3 (a) The motion model Ⅱ of MA cation; (b) Simulated 2H NMR spectra showing the effect of the wobbling motion in Fig. (a). In the simulation, σ increases from 0˚ to 20˚. The speeds of the rotation along the C-N bond and wobbling motion are both set to fast limit. Some atoms in the MA cation are omitted for clarity |
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