MAPbCl3钙钛矿中甲胺阳离子运动的固体2H NMR研究
Solid-state 2H NMR Study of the Motion of CH3NH3+ in MAPbCl3 Perovskite
MAPbCl3钙钛矿中甲胺阳离子运动的固体2H NMR研究 |
| 梁佳琪,乔文成,姚叶锋 |
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Solid-state 2H NMR Study of the Motion of CH3NH3+ in MAPbCl3 Perovskite |
| Jia-qi LIANG,Wen-cheng QIAO,Ye-feng YAO |
| 图2 MA在静止状态下和围绕C-N键（Cn轴）快速内旋转时的拟合2H NMR谱.在左侧MA的内旋转运动模型（模型Ⅰ）中，C-D键与Cn轴之间的夹角θ = 70˚，旋转速率为快极限（fast limit）.为了使图更加清晰，MA中部分原子被省略 |
| Fig.2 Simulated 2H NMR spectra showing the effect of the rotation along the Cn bond. The Cn denotes the rotation axis and θ = 70˚ denotes the open angle between the C-D bond and Cn. In the simulation, the speed of rotation is set to fast limit. Some atoms in the MA cation are omitted for clarity |
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