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三自旋体系核自旋单重态的制备与单重态二维谱的实现
胡凯瑞,杨雪,黄志明,辛家祥,魏达秀*(),姚叶锋*()
Preparing Nuclear Spin Singlet State in a Three-spin System and Its Application in 2D Spectrum
Kai-rui HU,Xue YANG,Zhi-ming HUANG,Jia-xiang XIN,Da-xiu WEI*(),Ye-feng YAO*()

图5. (a) pH 2.3时,NAA溶液经(1) OC、(2) OC′脉冲作用后的单重态NMR模拟谱图,以及它的(3)单脉冲1H NMR模拟谱和(4)单脉冲1H NMR实验谱;(b)利用OC′脉冲,将射频中心O1分别偏置(1) 10 Hz、(2) 5 Hz、(3) ?5 Hz、(4) ?10 Hz时得到的四组单重态NMR模拟谱图;(c) pH 5.5时,NAA溶液经OC′′脉冲作用后的(1)单重态模拟谱图以及(2)单脉冲1H NMR模拟谱

Fig.5. (a) Simulated singlet state spectra of NAA solution with pH of 2.3 obtained by (1) OC pulse sequence, (2) OC' pulse sequence, and its (3) simulated and (4) experimental single pulse 1H NMR spectra; (b) Four simulated singlet state spectra using OC' pulse sequence with offsetting the radio frequency center O1 of (1) 10 Hz, (2) 5 Hz, (3) ?5 Hz, (4) ?10 Hz, respectively; (c) Simulated (1) singlet state spectrum with OC′′ pulse and (2) single pulse 1H NMR spectrum of NAA solution with pH of 5.5