三自旋体系核自旋单重态的制备与单重态二维谱的实现
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胡凯瑞,杨雪,黄志明,辛家祥,魏达秀*( ),姚叶锋*( )
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Preparing Nuclear Spin Singlet State in a Three-spin System and Its Application in 2D Spectrum
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Kai-rui HU,Xue YANG,Zhi-ming HUANG,Jia-xiang XIN,Da-xiu WEI*( ),Ye-feng YAO*( )
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图2. (a) 优化控制(OC/OC′)脉冲序列. 其中优化控制脉冲的作用是实现单重态的制备与转化;CW与梯度场的结合可以保留单重态,并去除其它相干态. (b) OCI脉冲作用期间幅度随脉冲作用时间的变化. (c) OCI脉冲作用期间相位随脉冲作用时间的变化
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Fig.2. (a) Optimal control (OC/OC′) pulse sequence for preparing and converting nuclear spin singlet state. The combination of CW and gradient field can remove spin coherent-states and retain nuclear spin singlet state. (b) The amplitude of OCI pulse versus time while OCI works; (c) The phase of OCI pulse versus time while OCI works
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