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基于纯化学位移的同核二维正交相敏J分解核磁共振波谱
林晓晴,杜世佳,詹昊霖,黄玉清,陈忠*()
Two-Dimensional Homonuclear Orthogonal-Pattern Phase-Sensitive J-Resolved NMR Spectroscopy Based on Pure Shifts
Xiao-qing LIN,Shi-jia DU,Hao-lin ZHAN,Yu-qing HUANG,Zhong CHEN*()

图7. 应用于不均匀磁场下的高分辨2D J-编辑谱方法. (a)基于3D采样的HR-G-SERF实验序列,相位循环:Φ1 (x, -x), Φ2 (x), Φ3 (x, x, y, y, -x, -x, -y, -y), Φrec (x, -x, -x, x). (b)基于2D快速采样的AH-G-SERF实验序列,由ZS模块和G-SERF回波链模块组成设计的,相位循环:Φ1=Φ2=Φ3=Φrec=xΦ4J编辑回波链采样模块中以(x, x, x, x, -x, -x, -x, -x)N/2为循环.细绿色长条和粗绿色长条分别表示π/2和π非选择性脉冲,蓝色和红色填充形状表示的分别是用于选择特定质子和空间编码的π选择性脉冲;Gz为空间编码的弱梯度,G1G2G3G4为相干选择梯度(摘自文献[53])

Fig.7. High-resolution 2D J-edited spectroscopy applied in inhomogeneous magnetic fields. (a) HR-G-SERF sequence based on 3D acquisition. Phase cycling: Φ1 (x, -x), Φ2 (x), Φ3 (x, x, y, y, -x, -x, -y, -y), Φrec (x, -x, -x, x). (b) AH-G-SERF sequence based on accelerated 2D acquisition from the combination of ZS and G-SERF echo-train acquisition modules. Phase cycling: Φ1=Φ2=Φ3=Φrec=x, and Φ4 is set as a phase array of (x, x, x, x, -x, -x, -x, -x)N/2 in the J-edited echo-train acquisition module. Thin and fat green bars represent π/2 and π nonselective pulses. Blue and red shaped pulses indicate π selective pulses applied for inversing selected proton and spatial frequency encoding, respectively. Gz denotes the weak gradient for spatial frequency encoding. G1, G2, G3, and G4 are coherence-selection gradients (Excerpted from Ref.[53])