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基于纯化学位移的同核二维正交相敏J分解核磁共振波谱
林晓晴,杜世佳,詹昊霖,黄玉清,陈忠*()
Two-Dimensional Homonuclear Orthogonal-Pattern Phase-Sensitive J-Resolved NMR Spectroscopy Based on Pure Shifts
Xiao-qing LIN,Shi-jia DU,Hao-lin ZHAN,Yu-qing HUANG,Zhong CHEN*()

图5. (a) 单层激发和(b)多层激发的OPAM-2DJ实验的脉冲序列示意图.该序列由纯化学位移ZS模块和回波链J采样模块组成.绿色填充代表π/2和π非选择性脉冲;红色填充代表单色π脉冲;黄色填充代表多色π/2和π脉冲;Gz为与空间选层脉冲相匹配的弱梯度;G1G2G3G4是相干选择路径梯度;Φm, n为附加的傅里叶编码相位;序列的相位为:Φ1 (x, -x)、Φ2 (x)、Φ3 (x, x, y, y, -x, -x, -y, -y)、Φrec (x, y, y, x);Φ4在回波链J采样模块中,遵循(x, x, -x, -x)的相位(摘自文献[47])

Fig.5. Pulse sequences for (a) single-band and (b) multi-band OPAM-2DJ experiments. The sequence is constituted of ZS and echo-train J acquisition modules. Green bars denote π/2 and π nonselective pulses, respectively. The red-shaped pulse represents monochromatic π pulse. The yellow-shaped pulses represent polychromatic π/2 and π pulses. Gz indicates the weak gradient for extracting spatial slice-selective signals; G1, G2, G3, G4 are used for coherence pathway selection. Φm, n is the appended Fourier encoding phase. Phase cycling: Φ1 (x, -x), Φ2 (x), Φ3 (x, x, y, y, -x, -x, -y, -y), Φrec (x, y, y, x). Φ4 is varied as (x, x, -x, -x) in the echo-train J acquisition module (Excerpted from Ref. [47])