固体核磁共振技术在甲醇制烯烃反应中的应用
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高树树 1,2,徐舒涛 1,*( ),魏迎旭 1,刘中民 1
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Applications of Solid-State Nuclear Magnetic Resonance Spectroscopy in Methanol-to-Olefins Reaction
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Shu-shu GAO 1,2,Shu-tao XU 1,*( ),Ying-xu WEI 1,Zhong-min LIU 1
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图7. 298 K下SAPO-34的2D EXSY NMR谱图,平均每个笼内吸附3.6个氙原子,混合时间分别为(a) 1 ms、(b) 2 ms和(c) 10 ms;(d)单个SAPO-34晶体中Xen团簇可能的空间位置[82]
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Fig.7. 2D EXSY NMR spectra of xenon adsorbed in the SAPO-34 molecular sieve with an average loading of 3.6 xenon atoms per cage at 298 K with mixing times of (a) 1 ms, (b) 2 ms, and (c) 10 ms, respectively; (d) Possible spatial location of Xen clusters in a single SAPO-34 crystal[82]
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