Study on the Solvent Effect in  Acrylamide by NMR

Abstract

Abstract:

The “pseudo mirroring image” relationship between the resonance peaks of the two trans protons of acrylamide (AM) in CDCl₃and DMSO mixed solvent was studited as a function of the radio of the two solvents. The changes of chemical shifts in different solvents were studied by ¹H NMR and 2D NOESY. Variable temperature ¹H NMR indicated the formation of hydrogen bonds between -NH₂ of AM and the protons of residue water in solvent.

Key words: ¹H NMR, Acrylamide, non-proton polar solvent, dipole-dipole interaction

CLC Number:

O645

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YAN Xiu-Ling, SUN Wan-Fu, ZHAO Xin. Study on the Solvent Effect in Acrylamide by NMR[J]. Chinese Journal of Magnetic Resonance, 2005, 22(4): 429-435.

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References

[1] Ge X W，Ye Q，Xu X L，et al. Radiation copplymerization of acrylamide and cationic monomer in an inverse emulsion[J]. Polymer, 1998，39(10):1 917-1 920.

[2] Zhu L Y(朱麟勇)，Dai Y H(戴玉华)，Li M Z H(李妙贞)，et al. Association behaviors of dendritic polyether modified polyacrylamide with anionic surfacetant(树枝聚醚改性聚丙烯酰胺和阴离子表面活性剂的缔合行为)[J]. Acta Chimica Sinica(化学学报)，2003，61: 671-675.

[3] Zhang Jian-jun，Zhang Hai-feng，Wang Yin-tang. Study on the interactuions between acetoxime and some aromatic hydrocarbons by ¹H NMR[J]. Acta Phys-Chim Sin, 1993，9(1): 125.

[4] Zeng J C(曾竞成)，Shen L F(沈联芳)，Lu T B(鲁天保), et al. Dynamic ¹H NMR studies of solvent effect for benzoazacrown-ether in CDCl₃ solutions[J]. Acta Phys-Chim Sin(物理化学学报)，1988，4(3): 244-249.

[5] Zhang H F(张海峰）, Zhang J J（张建军）, Zhou Q Z（周清泽）. A study of the solvent effect of 2,2-DI(methylthylthio) vinyl phenyl ketone by ¹H NMR(2,2-二(甲硫基)乙烯基苯基酮\+1H NMR溶剂效应的研究)[J]. Chinese J Magn Reson(波谱学杂志）, 1997, 14(4): 363-366.

[6] Yan X L(闫秀玲）, Sun W F（孙万赋）, Tang J（唐军）, et al. A proton NMR study of PVA under UV irradiation(紫外光辐照聚乙烯醇的¹H NMR研究)[J]. Chinese J Magn Reson(波谱学杂志），2004，21（4）：493-498.

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