波谱学杂志 ›› 1986, Vol. 3 ›› Issue (1): 27-32.

• 研究论文 • 上一篇    下一篇

吖啶与脂肪醇的光化夺氢反应活泼自由基的ESR研究

周建威, 徐广智   

  1. 中国科学院化学研究所, 北京
  • 收稿日期:1985-08-26 出版日期:1986-03-05 发布日期:2018-01-23
  • 基金资助:
    中国科学院科学基金资助课题

ESR STUDY OF PHOTOCHEMICAL H-ABSTRACTION REACTION BETWEEN ACRIDINE AND ALCOHOLS

Zhou Jianwei, Xu Guangzhi   

  1. Institute of Chemistry, Academia Sinica, Beijing
  • Received:1985-08-26 Online:1986-03-05 Published:2018-01-23

摘要: 本文用自由基捕捉技术与ESR联用的方法,研究了吖啶与各种脂肪醇光化夺氢反应中产生的活泼自由基,并讨论了夺氢反应机理。

Abstract: The active free radicals generated in the Photochemical hydrogen abstraction reactions between acridine and aliphatic amines have been studied by the spin trapping technique and ESR method in this paper.The mechanism of hydrogen abstraction reactions have been discussed.