选择性远程DEPT NMR新技术用于culantraramine结构鉴定

波谱学杂志 ›› 1993, Vol. 10 ›› Issue (2): 189-194.

选择性远程DEPT NMR新技术用于culantraramine结构鉴定

缪振春, 吴文铸, 冯锐

军事医学科学院毒物药物研究所, 北京 100850

收稿日期:1992-05-07 修回日期:1992-08-10 出版日期:1993-06-05 发布日期:2018-01-20

STRUCTURE DETERMINATION AND SPECTRAL ASSIGMENT OF A BISHORDENINYL TERPENE ALKALOID BY SELECTIVE LONG-RANGE DEPT ¹³C NMR NEW TECHNIQUE

Miao Zhenchun, Wu Wenzhu, Feng Rui

Academy of Military Medical Science, Beijing 100850

Received:1992-05-07 Revised:1992-08-10 Online:1993-06-05 Published:2018-01-20

摘要/Abstract

摘要： 从中草药勒党植物中分得一个生物碱,选择性远程DEPT NMR新技术用于识别谱峰,连接被季碳、杂原子分隔的质子自旋系统,确定其结构如(1)所示。

关键词: 选择性远程DEPT NMR, 勒党生物碱, 化学结构测定

Abstract: An alkaloid was isolated from Zhanthoxylum avicennae (Lam). DC.Selective long-range DEPT ¹³C NMR new technique has been used to identify ¹³C nuclei and to connect spin systems separated by quaternary carbons and heteroatoms in the compound. Total assigment of ¹H and ¹³C NMR spectra of the compound were achieved. Its structure has been elucidated as (1).

Key words: Selective long-range DEPT ¹³C NMR, Bishordcninyl terpene alkaloid

缪振春, 吴文铸, 冯锐. 选择性远程DEPT NMR新技术用于culantraramine结构鉴定[J]. 波谱学杂志, 1993, 10(2): 189-194.

Miao Zhenchun, Wu Wenzhu, Feng Rui. STRUCTURE DETERMINATION AND SPECTRAL ASSIGMENT OF A BISHORDENINYL TERPENE ALKALOID BY SELECTIVE LONG-RANGE DEPT ¹³C NMR NEW TECHNIQUE[J]. Chinese Journal of Magnetic Resonance, 1993, 10(2): 189-194.